Articles producció científicaQuímica Analítica i Química Orgànica

Synthesis of a P-stereogenic PNPtBu,Ph ruthenium pincer complex and its application in asymmetric reduction of ketones

  • Identification data

    Identifier:  imarina:9285446
    Handle: https://hdl.handle.net/20.500.11797/imarina9285446
    Authors:  Arenas, I; Boutureira, O; Matheu, MI; Díaz, Y; Castillón, S
    Abstract:
    A novel P-stereogenic PNPtBu,Ph ruthenium complex has been synthesized and characterized enabling the asymmetric hydrogenation of a wide range of aromatic ketones with excellent catalytic activities (up to 98% conversion) and good levels of enantiodiscrimination (up to 95% ee). P-stereogenic PNPtBu,Ph Ru complex was for the first time synthesized and characterized and has proven to be an efficient catalyst for the asymmetric reduction of a wide range of ketones Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201500389
    APA: Arenas, I; Boutureira, O; Matheu, MI; Díaz, Y; Castillón, S (2015). Synthesis of a P-stereogenic PNPtBu,Ph ruthenium pincer complex and its application in asymmetric reduction of ketones. European Journal Of Organic Chemistry, 2015(17), 3666-3669. DOI: 10.1002/ejoc.201500389
    Paper original source: European Journal Of Organic Chemistry. 2015 (17): 3666-3669
    Article's DOI: 10.1002/ejoc.201500389
    Journal publication year: 2015-06-01
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2026-05-09
    URV's Author/s: Boutureira Martín, Omar / Castillón Miranda, Sergio / Díaz Giménez, María Yolanda / Matheu Malpartida, María Isabel
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Arenas, I; Boutureira, O; Matheu, MI; Díaz, Y; Castillón, S
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Interdisciplinar, Chemistry, organic, Biotecnología, Astronomia / física
    Author's mail: sergio.castillon@urv.cat, sergio.castillon@urv.cat, omar.boutureira@urv.cat, omar.boutureira@urv.cat, yolanda.diaz@urv.cat, yolanda.diaz@urv.cat, yolanda.diaz@urv.cat, maribel.matheu@urv.cat, maribel.matheu@urv.cat

  • Keywords:

    Ruthenium
    Pincer ligands
    Chiral alcohols
    Asymmetric hydrogenation
    Chemistry
    Organic
    Organic Chemistry
    Physical and Theoretical Chemistry
    Interdisciplinar
    Biotecnología
    Astronomia / física

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