Articles producció científica> Enginyeria Mecànica

Molar heat capacities of the mixture {1,8-cineole + ethanol} at several temperatures and atmospheric pressure

  • Identification data

    Identifier: imarina:9285459
  • Authors:

    Martínez-López JF
    Schneider S
    Salavera D
    Mainar AM
    Urieta JS
    Pardo JI
  • Others:

    Author, as appears in the article.: Martínez-López JF; Schneider S; Salavera D; Mainar AM; Urieta JS; Pardo JI
    Department: Enginyeria Mecànica
    URV's Author/s: Salavera Muñoz, Daniel
    Keywords: Temperature rise Temperature intervals Specific heat of solids Specific heat Molar heat capacity Molar heat capacities Mixtures Excess molar heat capacities Excess heat capacity Ethanol Cosmo-rs Composition ranges Atmospheric temperature Atmospheric pressure 1 ,8-cineole (1,8-cineole + ethanol) mixture
    Abstract: Molar heat capacities at atmospheric pressure have been determined every 5 K for the mixture {1,8-cineole (1) + ethanol (2)} in the temperature interval (304.7 to 324.5) K and the whole composition range with a Calvet type calorimeter Setaram C80. From the molar heat capacities, excess molar heat capacities have been calculated, their values being positive and increasing as the temperature rises. The solvation model COSMO-RS has been applied to predict the excess molar heat capacities. The model overestimates the values of the excess heat capacities but predicts well the trend of variation of the excess molar heat capacity with the temperature. © 2015 Elsevier Ltd. All rights reserved.
    Thematic Areas: Thermodynamics Química Physical and theoretical chemistry Medicina veterinaria Materials science (miscellaneous) Materials science (all) Materiais Interdisciplinar Geociências General materials science Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Biotecnología Atomic and molecular physics, and optics Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: daniel.salavera@urv.cat
    Author identifier: 0000-0003-0061-0581
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0021961415003341
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Journal Of Chemical Thermodynamics. 92 146-151
    APA: Martínez-López JF; Schneider S; Salavera D; Mainar AM; Urieta JS; Pardo JI (2016). Molar heat capacities of the mixture {1,8-cineole + ethanol} at several temperatures and atmospheric pressure. Journal Of Chemical Thermodynamics, 92(), 146-151. DOI: 10.1016/j.jct.2015.09.012
    Article's DOI: 10.1016/j.jct.2015.09.012
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    Publication Type: Journal Publications
  • Keywords:

    Atomic and Molecular Physics, and Optics,Chemistry, Physical,Materials Science (Miscellaneous),Physical and Theoretical Chemistry,Thermodynamics
    Temperature rise
    Temperature intervals
    Specific heat of solids
    Specific heat
    Molar heat capacity
    Molar heat capacities
    Mixtures
    Excess molar heat capacities
    Excess heat capacity
    Ethanol
    Cosmo-rs
    Composition ranges
    Atmospheric temperature
    Atmospheric pressure
    1 ,8-cineole
    (1,8-cineole + ethanol) mixture
    Thermodynamics
    Química
    Physical and theoretical chemistry
    Medicina veterinaria
    Materials science (miscellaneous)
    Materials science (all)
    Materiais
    Interdisciplinar
    Geociências
    General materials science
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Biotecnología
    Atomic and molecular physics, and optics
    Astronomia / física
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