Articles producció científica> Enginyeria Mecànica

Molar heat capacities of the mixture {1,8-cineole + ethanol} at several temperatures and atmospheric pressure

  • Identification data

    Identifier: imarina:9285459
  • Authors:

    Martínez-López JF
    Schneider S
    Salavera D
    Mainar AM
    Urieta JS
    Pardo JI
  • Others:

    Author, as appears in the article.: Martínez-López JF; Schneider S; Salavera D; Mainar AM; Urieta JS; Pardo JI
    Department: Enginyeria Mecànica
    URV's Author/s: Salavera Muñoz, Daniel
    Keywords: (1,8-cineole + ethanol) mixture 1 ,8-cineole Atmospheric pressure Atmospheric temperature Composition ranges Cosmo-rs Ethanol Excess heat capacity Excess molar heat capacities Mixtures Molar heat capacities Molar heat capacity Specific heat Specific heat of solids Temperature intervals Temperature rise
    Abstract: Molar heat capacities at atmospheric pressure have been determined every 5 K for the mixture {1,8-cineole (1) + ethanol (2)} in the temperature interval (304.7 to 324.5) K and the whole composition range with a Calvet type calorimeter Setaram C80. From the molar heat capacities, excess molar heat capacities have been calculated, their values being positive and increasing as the temperature rises. The solvation model COSMO-RS has been applied to predict the excess molar heat capacities. The model overestimates the values of the excess heat capacities but predicts well the trend of variation of the excess molar heat capacity with the temperature. © 2015 Elsevier Ltd. All rights reserved.
    Thematic Areas: Astronomia / física Atomic and molecular physics, and optics Biotecnología Chemistry, physical Ciência de alimentos Ciências agrárias i Ciências ambientais Ciências biológicas i Ciências biológicas ii Engenharias ii Engenharias iii General materials science Geociências Interdisciplinar Materiais Materials science (all) Materials science (miscellaneous) Medicina veterinaria Physical and theoretical chemistry Química Thermodynamics
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: daniel.salavera@urv.cat
    Author identifier: 0000-0003-0061-0581
    Record's date: 2023-02-23
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0021961415003341
    Papper original source: Journal Of Chemical Thermodynamics. 92 146-151
    APA: Martínez-López JF; Schneider S; Salavera D; Mainar AM; Urieta JS; Pardo JI (2016). Molar heat capacities of the mixture {1,8-cineole + ethanol} at several temperatures and atmospheric pressure. Journal Of Chemical Thermodynamics, 92(), 146-151. DOI: 10.1016/j.jct.2015.09.012
    Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1016/j.jct.2015.09.012
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    Publication Type: Journal Publications
  • Keywords:

    Atomic and Molecular Physics, and Optics,Chemistry, Physical,Materials Science (Miscellaneous),Physical and Theoretical Chemistry,Thermodynamics
    (1,8-cineole + ethanol) mixture
    1 ,8-cineole
    Atmospheric pressure
    Atmospheric temperature
    Composition ranges
    Cosmo-rs
    Ethanol
    Excess heat capacity
    Excess molar heat capacities
    Mixtures
    Molar heat capacities
    Molar heat capacity
    Specific heat
    Specific heat of solids
    Temperature intervals
    Temperature rise
    Astronomia / física
    Atomic and molecular physics, and optics
    Biotecnología
    Chemistry, physical
    Ciência de alimentos
    Ciências agrárias i
    Ciências ambientais
    Ciências biológicas i
    Ciências biológicas ii
    Engenharias ii
    Engenharias iii
    General materials science
    Geociências
    Interdisciplinar
    Materiais
    Materials science (all)
    Materials science (miscellaneous)
    Medicina veterinaria
    Physical and theoretical chemistry
    Química
    Thermodynamics
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