Author, as appears in the article.: Khoiru Wihadi MN; Haioka T; Kojima T; López X; Ueda T; Sano T; Sadakane M
Department: Química Física i Inorgànica
URV's Author/s: López Fernández, Javier
Keywords: Thermal-stability Substitution Self-assembly Preyssler-type phosphotungstate Polyoxometalates Molybdate substitution self-assembly screening model protection preyssler-type phosphotungstate polyoxometalates polyoxometalate performance esterification efficient catalyst coordination polymers cations acid catalyst
Abstract: We report the synthesis of multi-Mo-substituted Preyssler-type phosphotungstates, [P5W30-xMoxO110Na(H2O)]14−, with different amounts of incorporated Mo via the hydrothermal reactions of H3PO4, Na2WO4, and Na2MoO4; and characterization by 31P nuclear magnetic resonance (NMR), Fourier-transform infrared (FT-IR), elemental analysis, electrospray ionization-mass spectrometry (ESI-MS), and cyclic voltammetry. The number of substituted Mo increases by increasing the amount of Na2MoO4 in the reaction mixture, and in the [P5W30-xMoxO110Na(H2O)]14−, up to penta-Mo-substituted species can be produced as mixtures of isomers with different Mo numbers and Mo positions. Single crystal X-ray structure analysis and density functional theory calculation indicate that the most suitable substitution position is the belt position.
Thematic Areas: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: javier.lopez@urv.cat
Author identifier: 0000-0003-0322-6796
Record's date: 2024-07-27
Papper version: info:eu-repo/semantics/submittedVersion
Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.202200533
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: European Journal Of Inorganic Chemistry. 2022 (36):
APA: Khoiru Wihadi MN; Haioka T; Kojima T; López X; Ueda T; Sano T; Sadakane M (2022). Synthesis and Structural Characterization of Multi-Molybdenum-Substituted Preyssler-type Phosphotungstates. European Journal Of Inorganic Chemistry, 2022(36), -. DOI: 10.1002/ejic.202200533
Article's DOI: 10.1002/ejic.202200533
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV