Author, as appears in the article.: Mella, Claudio; Pecchi, Gina; Godard, Cyril; Claver, Carmen; Marquez, Abdiel; Campos, Cristian H
Department: Química Física i Inorgànica
URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
Keywords: Synthetic route Pd(ii)-schiff base complex Palladium complex Metal-containing monomer Immobilization synthetic route schiff-base reusable catalyst palladium complex mizoroki-heck metal-containing monomer merrifield resin heterogeneous catalysts grubbs catalysts green synthesis coupling reaction containing monomers
Abstract: A critical query on literature is the approach used to immobilize homogeneous catalysts to improve their efficiency and recyclability. This work aims to compare the immobilization level of a kind of Pd-N,N′-bis(salicylidene)-o-phenylenediamine complex on high surfaces of polymeric resins to provide heterogenous catalysts for Mizorocki-Heck reaction. The preparation method involves two strategies: (i) polymerization of the ligand before the complex-synthesis in a “multi-step (MS)” approach and (ii) a direct “one-step” (OS) immobilization by polymerization of the metal-containing monomers (MCMs) as co-monomer. Both approaches effectively yield polymers with a larger surface area, over 700 m2 g−1, and suitable thermic properties to use in the proposed reaction. In addition, the characterization of the polymers by XRD, XPS, and TEM demonstrates notable differences in Pd species on polymer support associated with the methodological approach to immobilizing the metal complex.
Thematic Areas: Surfaces, coatings and films Química Polymers and plastics Polymer science Odontología Nutrição Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar Geociências General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: cyril.godard@urv.cat carmen.claver@urv.cat
Author identifier: 0000-0001-5762-4904 0000-0002-2518-7401
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Journal Of Applied Polymer Science. 140 (10):
APA: Mella, Claudio; Pecchi, Gina; Godard, Cyril; Claver, Carmen; Marquez, Abdiel; Campos, Cristian H (2023). Immobilized Pd metal-complex on polymeric resin with high surface areas for recyclable catalyst: Effect of the immobilization method on nature of palladium species. Journal Of Applied Polymer Science, 140(10), -. DOI: 10.1002/app.53608
Entity: Universitat Rovira i Virgili
Journal publication year: 2023
Publication Type: Journal Publications
Repositori URV