Articles producció científicaQuímica Analítica i Química Orgànica

Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids

  • Identification data

    Identifier:  imarina:9292147
    Handle: https://hdl.handle.net/20.500.11797/imarina9292147
    Authors:  Palomo E; Sharma AK; Wang Z; Jiang L; Maseras F; Suero MG
    Abstract:
    We describe the first catalytic generation of Fischer-type acyloxy Rh(II)-carbenes from carboxylic acids and Rh(II)-carbynoids. This novel class of transient donor/acceptor Rh(II)-carbenes evolved through a cyclopropanation process providing access to densely functionalized cyclopropyl-fused lactones with excellent diastereoselectivity. DFT calculations allowed the analysis of the properties of Rh(II)-carbynoids and acyloxy Rh(II)-carbenes as well as the characterization of the mechanism.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/jacs.3c00012
    APA: Palomo E; Sharma AK; Wang Z; Jiang L; Maseras F; Suero MG (2023). Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids. Journal Of The American Chemical Society, 145(9), 4975-4981. DOI: 10.1021/jacs.3c00012
    Paper original source: Journal Of The American Chemical Society. 145 (9): 4975-4981
    Article's DOI: 10.1021/jacs.3c00012
    Journal publication year: 2023
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2024-11-23
    URV's Author/s: Palomo Martinez, Eric
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Palomo E; Sharma AK; Wang Z; Jiang L; Maseras F; Suero MG
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Astronomia / física, Biochemistry, Catalysis, Chemistry, Chemistry (all), Chemistry (miscellaneous), Chemistry, multidisciplinary, Ciência de alimentos, Ciências agrárias i, Ciências biológicas i, Ciências biológicas ii, Colloid and surface chemistry, Engenharias ii, Engenharias iii, Engenharias iv, Farmacia, General chemistry, Interdisciplinar, Materiais, Química
    Author's mail: eric.palomo@estudiants.urv.cat

  • Keywords:

    Clean water and sanitation
    Biochemistry
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Colloid and Surface Chemistry
    Astronomia / física
    Chemistry (all)
    Ciência de alimentos
    Ciências agrárias i
    Ciências biológicas i
    Ciências biológicas ii
    Engenharias ii
    Engenharias iii
    Engenharias iv
    Farmacia
    General chemistry
    Interdisciplinar
    Materiais
    Química

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