Author, as appears in the article.: Medina-Gil, T; Sadurní, A; Hammarback, LA; Echavarren, AM
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO / Sadurní Parera, Anna
Keywords: Gold catalysis Enantioselectivecatalysis Chromanes Aryloxycyclization Alkynes Alkenes Acetylene 2+2 cycloaddition
Abstract: Acetylene gas isan important feedstock for chemical production,although it is underutilized in organic synthesis. We have developedan intermolecular gold(I)-catalyzed alkyne/alkene reaction of o-allylphenols with acetylene gas that gives rise to chromanesby a stereospecific aryloxycyclization through the nucleophilic regioselectiveopening of cyclopropyl gold(I)-carbene intermediates. The syntheticapplication of this method was demonstrated in the late-stage functionalizationof the natural product lapachol.
Thematic Areas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: anna.sadurni@urv.cat antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2024-01-13
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/acscatal.3c02461
Papper original source: Acs Catalysis. 13 (16): 10751-10755
APA: Medina-Gil, T; Sadurní, A; Hammarback, LA; Echavarren, AM (2023). Gold(I)-Catalyzed Intermolecular Aryloxyvinylation with Acetylene Gas. Acs Catalysis, 13(16), 10751-10755. DOI: 10.1021/acscatal.3c02461
Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1021/acscatal.3c02461
Entity: Universitat Rovira i Virgili
Journal publication year: 2023
Publication Type: Journal Publications
Repositori URV