Author, as appears in the article.: García-Padilla, E; Maseras, F; Echavarren, AM
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO / García Padilla, Eduardo
Keywords: Skeletal reorganization Rearrangements Platinum Metal carbenes Mechanisms Gold-catalyzed cycloisomerization Gold carbenes Enynes Dft mechanisticstudy Dft mechanistic study Cycloisomerization Cyclobutenes Cyclization Conversion Bronsted acid 1,5-enynes
Abstract: We identify the factors that rule the selectivity insingle-cleavageskeletal rearrangements promoted by gold(I) catalysts. We find thatstereoconvergence is enabled by a rotational equilibrium when electron-richsubstituents are used. The anomalous Z-selectiveskeletal rearrangement is found to be due to electronic factors, whereas endo-selectivity depends on both steric and electronic factors.
Thematic Areas: Physical and theoretical chemistry Organic chemistry Inorganic chemistry Chemistry, multidisciplinary
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antoniomaria.echavarren@urv.cat eduardo.garcia@estudiants.urv.cat
Author identifier: 0000-0002-6418-7930 0000-0001-9715-7992
Record's date: 2024-08-03
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/acsorginorgau.3c00028
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Acs Organic And Inorganic Au. 3 (5): 312-320
APA: García-Padilla, E; Maseras, F; Echavarren, AM (2023). Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture. Acs Organic And Inorganic Au, 3(5), 312-320. DOI: 10.1021/acsorginorgau.3c00028
Article's DOI: 10.1021/acsorginorgau.3c00028
Entity: Universitat Rovira i Virgili
Journal publication year: 2023
Publication Type: Journal Publications
Repositori URV