Articles producció científicaQuímica Analítica i Química Orgànica

Gold(I)-Catalyzed 1

  • Identification data

    Identifier:  imarina:9329033
    Handle: https://hdl.handle.net/20.500.11797/imarina9329033
    Authors:  Garcia-Padilla, Eduardo; Maseras, Feliu; Echavarren, Antonio M
    Abstract:
    We identify the factors that rule the selectivity insingle-cleavageskeletal rearrangements promoted by gold(I) catalysts. We find thatstereoconvergence is enabled by a rotational equilibrium when electron-richsubstituents are used. The anomalous Z-selectiveskeletal rearrangement is found to be due to electronic factors, whereas endo-selectivity depends on both steric and electronic factors.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acsorginorgau.3c00028
    APA: Garcia-Padilla, Eduardo; Maseras, Feliu; Echavarren, Antonio M (2023). Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture. Acs Organic And Inorganic Au, 3(5), 312-320. DOI: 10.1021/acsorginorgau.3c00028
    Paper original source: Acs Organic And Inorganic Au. 3 (5): 312-320
    Article's DOI: 10.1021/acsorginorgau.3c00028
    Journal publication year: 2023
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO / García Padilla, Eduardo
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Garcia-Padilla, Eduardo; Maseras, Feliu; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Inorganic chemistry, Chemistry, multidisciplinary
    Author's mail: antoniomaria.echavarren@urv.cat, eduardo.garcia@estudiants.urv.cat

  • Keywords:

    Skeletal reorganization
    Rearrangements
    Platinum
    Metal carbenes
    Mechanisms
    Gold-catalyzed cycloisomerization
    Gold carbenes
    Enynes
    Dft mechanisticstudy
    Dft mechanistic study
    Cycloisomerization
    Cyclobutenes
    Cyclization
    Conversion
    Bronsted acid
    5-enynes
    Chemistry
    Multidisciplinary
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry

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