Author, as appears in the article.: Gaydou, Morgane; Echavarren, Antonio M
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO
Keywords: Rearrangement Heterocycles Gold Cycloadditions Azides heterocycles gold cycloadditions azides
Abstract: Golden duality: Tetrazoles are formed by the reaction of alkynes with TMSN3 (TMS=trimethylsilyl) in the presence of iPrOH and the gold(I) catalyst [JohnPhosAu(MeCN)]SbF6. In this transformation gold plays a dual role, first activating the alkyne and then generating a Brønsted acid in situ. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thematic Areas: Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2025-02-19
Paper version: info:eu-repo/semantics/publishedVersion
Paper original source: Angewandte Chemie (International Ed. Print). 52 (50): 13468-13471
APA: Gaydou, Morgane; Echavarren, Antonio M (2013). Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage. Angewandte Chemie (International Ed. Print), 52(50), 13468-13471. DOI: 10.1002/anie.201308076
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2013
Publication Type: Journal Publications
Repositori URV