Articles producció científicaQuímica Analítica i Química Orgànica

Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage

  • Identification data

    Identifier:  imarina:9368688
    Handle: https://hdl.handle.net/20.500.11797/imarina9368688
    Authors:  Gaydou, M; Echavarren, AM
    Abstract:
    Golden duality: Tetrazoles are formed by the reaction of alkynes with TMSN3 (TMS=trimethylsilyl) in the presence of iPrOH and the gold(I) catalyst [JohnPhosAu(MeCN)]SbF6. In this transformation gold plays a dual role, first activating the alkyne and then generating a Brønsted acid in situ. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201308076
    APA: Gaydou, M; Echavarren, AM (2013). Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage. Angewandte Chemie (International Ed. Print), 52(50), 13468-13471. DOI: 10.1002/anie.201308076
    Paper original source: Angewandte Chemie (International Ed. Print). 52 (50): 13468-13471
    Article's DOI: 10.1002/anie.201308076
    Journal publication year: 2013-12-09
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Gaydou, M; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: General medicine, General chemistry, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Rearrangement
    Heterocycles
    Gold
    Cycloadditions
    Azides
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    General medicine
    General chemistry
    Chemistry (all)
    Astronomia / física

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