Articles producció científicaQuímica Analítica i Química Orgànica

Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage

  • Identification data

    Identifier:  imarina:9368688
    Handle: https://hdl.handle.net/20.500.11797/imarina9368688
    Authors:  Gaydou, Morgane; Echavarren, Antonio M
    Abstract:
    Golden duality: Tetrazoles are formed by the reaction of alkynes with TMSN3 (TMS=trimethylsilyl) in the presence of iPrOH and the gold(I) catalyst [JohnPhosAu(MeCN)]SbF6. In this transformation gold plays a dual role, first activating the alkyne and then generating a Brønsted acid in situ. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201308076
    APA: Gaydou, Morgane; Echavarren, Antonio M (2013). Gold-catalyzed synthesis of tetrazoles from alkynes by Cï£ ¿C bond cleavage. Angewandte Chemie (International Ed. Print), 52(50), 13468-13471. DOI: 10.1002/anie.201308076
    Paper original source: Angewandte Chemie (International Ed. Print). 52 (50): 13468-13471
    Article's DOI: 10.1002/anie.201308076
    Journal publication year: 2013
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-19
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Gaydou, Morgane; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Medicina ii, Medicina i, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias ii, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat

  • Keywords:

    Rearrangement
    Heterocycles
    Gold
    Cycloadditions
    Azides
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry (all)
    Astronomia / física

  • Documents:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar