Articles producció científicaQuímica Analítica i Química Orgànica

Three-Component Gold(I)-Catalyzed Alkoxyvinylation

  • Identification data

    Identifier:  imarina:9378613
    Handle: https://hdl.handle.net/20.500.11797/imarina9378613
    Authors:  Hammarback, LA; Medina-Gil, T; Sadurní, A; Echavarren, AM
    Abstract:
    Acetylene has been underexploited despite being a highly valuable feedstock for chemical synthesis. We have developed the first true gold(I)-catalyzed intermolecular three-component reaction between acetylene, alkenes, and alcohols to afford beta-vinyl hemiaminal scaffolds from N-vinyl amides. Unusual biscyclopropyl and 3-vinyl N-heterocyclic scaffolds were obtained through the incorporation of a second N-vinyl unit or tethered alkene into the starting material.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acs.orglett.4c02102
    APA: Hammarback, LA; Medina-Gil, T; Sadurní, A; Echavarren, AM (2024). Three-Component Gold(I)-Catalyzed Alkoxyvinylation. Organic Letters, 26(30), 6375-6379. DOI: 10.1021/acs.orglett.4c02102
    Paper original source: Organic Letters. 26 (30): 6375-6379
    Article's DOI: 10.1021/acs.orglett.4c02102
    Journal publication year: 2024-07-18
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO / Medina Gil, Tania / Sadurní Parera, Anna
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Hammarback, LA; Medina-Gil, T; Sadurní, A; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, General medicine, Chemistry, organic, Biotecnología, Biodiversidade, Biochemistry
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat, tania.medina@estudiants.urv.cat

  • Keywords:

    Intermolecular 2+2 cycloaddition
    Gold
    Acetylen
    Biochemistry
    Chemistry
    Organic
    Organic Chemistry
    Physical and Theoretical Chemistry
    General medicine
    Biotecnología
    Biodiversidade

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