Author, as appears in the article.: Hammarback, L Anders; Medina-Gil, Tania; Sadurni, Anna; Echavarren, Antonio M
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO / Medina Gil, Tania / Sadurní Parera, Anna
Keywords: Acetylen Gold Intermolecular 2+2 cycloaddition
Abstract: Acetylene has been underexploited despite being a highly valuable feedstock for chemical synthesis. We have developed the first true gold(I)-catalyzed intermolecular three-component reaction between acetylene, alkenes, and alcohols to afford beta-vinyl hemiaminal scaffolds from N-vinyl amides. Unusual biscyclopropyl and 3-vinyl N-heterocyclic scaffolds were obtained through the incorporation of a second N-vinyl unit or tethered alkene into the starting material.
Thematic Areas: Biochemistry Biodiversidade Biotecnología Chemistry, organic Ciências agrárias i Ciências biológicas i Ciências biológicas ii Farmacia General medicine Interdisciplinar Materiais Medicina i Medicina ii Organic chemistry Physical and theoretical chemistry Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: tania.medina@estudiants.urv.cat antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2025-02-18
Paper version: info:eu-repo/semantics/publishedVersion
Paper original source: Organic Letters. 26 (30): 6375-6379
APA: Hammarback, L Anders; Medina-Gil, Tania; Sadurni, Anna; Echavarren, Antonio M (2024). Three-Component Gold(I)-Catalyzed Alkoxyvinylation. Organic Letters, 26(30), 6375-6379. DOI: 10.1021/acs.orglett.4c02102
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2024
Publication Type: Journal Publications
Repositori URV