Articles producció científicaQuímica Física i Inorgànica

From Alkenes to Cyclic Carbonates with a Stable Iron-Cross-Bridged Cyclam Catalyst

  • Identification data

    Identifier:  imarina:9378967
    Handle: https://hdl.handle.net/20.500.11797/imarina9378967
    Authors:  Bin Yeamin, M; Annunziata, A; Ruffo, F; Masdeu-Bultó, AM
    Abstract:
    A stable iron(III) complex with the cross-bridged cyclam 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane catalyzes the epoxidation of aromatic alkenes and the fixation of CO2 into cyclic carbonates. Best results were obtained for styrene conversion to styrene carbonate. An iron(III) complex with a cross-bridged cyclam ligand catalyzes the epoxidation of aromatic alkenes and the fixation of CO2 into cyclic carbonates. The one-pot or stepwise transformation of styrene to styrene carbonate was also achieved (15-24 % GC yield). image

  • Others:

    APA: Bin Yeamin, M; Annunziata, A; Ruffo, F; Masdeu-Bultó, AM (2024). From Alkenes to Cyclic Carbonates with a Stable Iron-Cross-Bridged Cyclam Catalyst. Chemistryselect, 9(29), e202400426-. DOI: 10.1002/slct.202400426
    Paper original source: Chemistryselect. 9 (29): e202400426-
    Article's DOI: 10.1002/slct.202400426
    Journal publication year: 2024-08-05
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: Masdeu Bultó, Anna Maria / Yeamin, MD Bin
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Bin Yeamin, M; Annunziata, A; Ruffo, F; Masdeu-Bultó, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: General chemistry, Ciências agrárias i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Administração pública e de empresas, ciências contábeis e turismo
    Author's mail: annamaria.masdeu@urv.cat, annamaria.masdeu@urv.cat

  • Keywords:

    Styrene carbonate
    Oxidation
    Olefins
    Manganese(iii
    Iron(iii) complexes
    Iron catalysts
    Epoxides
    Epoxidation
    Epoxidatio
    Dioxide
    Cyclic carbonates
    Cyclam
    Coupling reaction
    Co2
    Carbon dioxide
    Chemistry (Miscellaneous)
    Chemistry
    Multidisciplinary
    General chemistry
    Ciências agrárias i
    Chemistry (all)
    Administração pública e de empresas
    ciências contábeis e turismo

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