Articles producció científica> Química Física i Inorgànica

Growth, spectroscopy and 2 μm laser operation of monoclinic Tm3+:ZnWO4 crystal

  • Identification data

    Identifier: imarina:9382529
    Authors:
    Elabedine, Ghassen ZinSubbotin, KirillLoiko, PavelPan, ZhongbenEremeev, KirillZimina, YuliaDidenko, YanaPavlov, SergeiTitov, AnatolyDunina, ElenaFomicheva, LiudmilaBraud, AlainSole, Rosa MariaAguilo, MagdalenaDiaz, FrancescChen, WeidongVolkov, PavelMateos, Xavier
    Abstract:
    We report on the crystal growth, polarized spectroscopy, and laser operation of monoclinic Tm3+, Na+(Li+) codoped zinc monotungstate (ZnWO4) crystals. The Li+ codoping with an optimized Tm/Li ratio enables almost complete local charge compensation leading to better crystal quality, higher Tm segregation coefficient, and longer luminescence lifetime and ultimately the demonstration of laser operation. The modified Judd-Ofelt theory was employed to calculate the Tm3+ transition probabilities yielding a radiative lifetime of the F-3(4) state of 2.59 ms. The corresponding intensity parameters are Omega(2) = 5.194, Omega(4) = 0.658, Omega(6) = 0.471 [10(-20) cm(2)] and alpha = 0.110 [10(-4) cm]. Tm,Li:ZnWO4 features strongly polarized emission spectra extending beyond 2 mu m owing to a large total Stark splitting of the ground-state, Delta E (H-3(6)) = 644 cm(-1). The stimulated-emission cross-section in this spectral range reaches 0.47 x 10(-20) cm(2) at 2015 nm for light polarization E || N-p. The continuous-wave Tm,Li:ZnWO4 laser generated 282 mW at 1.98 mu m with a slope efficiency of 14.7 %, and laser emission at 2.03 mu m was also achieved.
  • Others:

    Author, as appears in the article.: Elabedine, Ghassen Zin; Subbotin, Kirill; Loiko, Pavel; Pan, Zhongben; Eremeev, Kirill; Zimina, Yulia; Didenko, Yana; Pavlov, Sergei; Titov, Anatoly; Dunina, Elena; Fomicheva, Liudmila; Braud, Alain; Sole, Rosa Maria; Aguilo, Magdalena; Diaz, Francesc; Chen, Weidong; Volkov, Pavel; Mateos, Xavier
    Department: Química Física i Inorgànica
    URV's Author/s: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Solé Cartañà, Rosa Maria / Zin Elabedine, Ghassen
    Keywords: Znwo4 Thulium ions Spectra Solid-state lasers Solid-state laser Optical spectroscopy Luminescence Laser materials Klu(wo4)(2) Judd-ofelt theory Ions Intensities Er3 Absorption
    Abstract: We report on the crystal growth, polarized spectroscopy, and laser operation of monoclinic Tm3+, Na+(Li+) codoped zinc monotungstate (ZnWO4) crystals. The Li+ codoping with an optimized Tm/Li ratio enables almost complete local charge compensation leading to better crystal quality, higher Tm segregation coefficient, and longer luminescence lifetime and ultimately the demonstration of laser operation. The modified Judd-Ofelt theory was employed to calculate the Tm3+ transition probabilities yielding a radiative lifetime of the F-3(4) state of 2.59 ms. The corresponding intensity parameters are Omega(2) = 5.194, Omega(4) = 0.658, Omega(6) = 0.471 [10(-20) cm(2)] and alpha = 0.110 [10(-4) cm]. Tm,Li:ZnWO4 features strongly polarized emission spectra extending beyond 2 mu m owing to a large total Stark splitting of the ground-state, Delta E (H-3(6)) = 644 cm(-1). The stimulated-emission cross-section in this spectral range reaches 0.47 x 10(-20) cm(2) at 2015 nm for light polarization E || N-p. The continuous-wave Tm,Li:ZnWO4 laser generated 282 mW at 1.98 mu m with a slope efficiency of 14.7 %, and laser emission at 2.03 mu m was also achieved.
    Thematic Areas: Spectroscopy Química Physical and theoretical chemistry Physical and theoretical c Organic chemistry Optics Odontología Medicina ii Materials science, multidisciplinary Materials science Materiais Interdisciplinar Inorganic chemistry General computer science Engenharias iv Engenharias iii Engenharias ii Electronic, optical and magnetic materials Electrical and electronic engineering Computer science (miscellaneous) Ciências ambientais Ciência de alimentos Biotecnología Biodiversidade Atomic and molecular physics, and optics Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: magdalena.aguilo@urv.cat rosam.sole@urv.cat xavier.mateos@urv.cat f.diaz@urv.cat
    Author identifier: 0000-0001-6130-9579 0000-0002-5769-4141 0000-0003-1940-1990 0000-0003-4581-4967
    Record's date: 2024-10-05
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/pii/S0925346724012229?via%3Dihub
    Papper original source: Optical Materials. 157 116039-
    APA: Elabedine, Ghassen Zin; Subbotin, Kirill; Loiko, Pavel; Pan, Zhongben; Eremeev, Kirill; Zimina, Yulia; Didenko, Yana; Pavlov, Sergei; Titov, Anatoly; (2024). Growth, spectroscopy and 2 μm laser operation of monoclinic Tm3+:ZnWO4 crystal. Optical Materials, 157(), 116039-. DOI: 10.1016/j.optmat.2024.116039
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1016/j.optmat.2024.116039
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2024
    Publication Type: Journal Publications
  • Keywords:

    Atomic and Molecular Physics, and Optics,Computer Science (Miscellaneous),Electrical and Electronic Engineering,Electronic, Optical and Magnetic Materials,Inorganic Chemistry,Materials Science,Materials Science, Multidisciplinary,Optics,Organic Chemistry,Physical and Theoretical C,Physical and Theoretical Chemistry,Spectroscopy
    Znwo4
    Thulium ions
    Spectra
    Solid-state lasers
    Solid-state laser
    Optical spectroscopy
    Luminescence
    Laser materials
    Klu(wo4)(2)
    Judd-ofelt theory
    Ions
    Intensities
    Er3
    Absorption
    Spectroscopy
    Química
    Physical and theoretical chemistry
    Physical and theoretical c
    Organic chemistry
    Optics
    Odontología
    Medicina ii
    Materials science, multidisciplinary
    Materials science
    Materiais
    Interdisciplinar
    Inorganic chemistry
    General computer science
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Electronic, optical and magnetic materials
    Electrical and electronic engineering
    Computer science (miscellaneous)
    Ciências ambientais
    Ciência de alimentos
    Biotecnología
    Biodiversidade
    Atomic and molecular physics, and optics
    Astronomia / física
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