Author, as appears in the article.: Alvaro-Martins, Maria J; Sanchez, Jose G; Lavarda, Giulia; Molina, Desire; Pallares, Josep; Torres, Tomas; Marsal, Lluis F; Sastre-Santos, Angela
Department: Enginyeria Electrònica, Elèctrica i Automàtica
URV's Author/s: Marsal Garví, Luis Francisco / Pallarès Marzal, Josep / SANCHEZ LÓPEZ, JOSÉ GUADALUPE
Keywords: π -systems boron subphthalocyanines core efficient infinity-systems interface non-fullerene acceptor organic solar cells performance subphthalocyanines π -systems Boron subphthalocyanines Core Diketopyrrolopyrroles Efficient Hole-transport layer Infinity-systems Interface Non-fullerene acceptor Organic solar cells Performance Subphthalocyanine Subphthalocyanines Π-systems
Abstract: Four star-shaped electron acceptors (C-1-OPh, C-3-OPh, C-1-Cl and C-3-Cl) based on a subphthalocyanine core bearing three diketopyrrolopyrrole wings linked by an acetylene bridge have been synthesized. These derivatives feature two different axial substituents (i. e., 4-tert-butylphenoxy (OPh) or chlorine (Cl)) and for each of them, both the C-1 and the C-3 regioisomers have been investigated. The four compounds exhibit a broad absorption band in the 450-700 nm region, with bandgap values near to 2 eV. These materials were applied in the active layer of inverted bulk-heterojunction polymer solar cells in combination with the donor polymer PBDB-T. Derivatives bearing the OPh axial group showed the best performances, with C-1-OPh being the most promising with a PCE of 3.27 % and a V-oc as high as 1.17 V. Despite presenting the widest absorption range, the photovoltaic results obtained with C-1-Cl turned out to be the lowest (PCE=1.01 %).
Thematic Areas: Chemistry (all) Chemistry (miscellaneous) Chemistry, multidisciplinary General chemistry Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: lluis.marsal@urv.cat josep.pallares@urv.cat
Author identifier: 0000-0002-5976-1408 0000-0001-7221-5383
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.202100103
Papper original source: Chempluschem. 86 (10): 1360-1361
APA: Alvaro-Martins, Maria J; Sanchez, Jose G; Lavarda, Giulia; Molina, Desire; Pallares, Josep; Torres, Tomas; Marsal, Lluis F; Sastre-Santos, Angela (2021). Subphthalocyanine-Diketopyrrolopyrrole Conjugates: 3D Star-Shaped Systems as Non-Fullerene Acceptors in Polymer Solar Cells with High Open-Circuit Voltage. Chempluschem, 86(10), 1360-1361. DOI: 10.1002/cplu.202100103
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1002/cplu.202100103
Entity: Universitat Rovira i Virgili
Journal publication year: 2021
Publication Type: Journal Publications
Repositori URV