Author, as appears in the article.: Obradors, Carla; Echavarren, Antonio M
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO
Keywords: Terminal alkynes Structural-characterizatio Solution behavior Skeletal rearrangement Ray crystal-structures One-pot synthesis N-heterocyclic carbene Intermolecular 2+2 cycloaddition Highly efficient Gold(i)-catalyzed cyclizations
Abstract: Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.
Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2024-11-09
Papper version: info:eu-repo/semantics/publishedVersion
Papper original source: Chemical Communications. 50 (1): 16-28
APA: Obradors, Carla; Echavarren, Antonio M (2014). Intriguing mechanistic labyrinths in gold(I) catalysis. Chemical Communications, 50(1), 16-28. DOI: 10.1039/c3cc45518a
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2014
Publication Type: Journal Publications
Repositori URV