Articles producció científicaQuímica Analítica i Química Orgànica

Intriguing mechanistic labyrinths in gold(I) catalysis

  • Identification data

    Identifier:  imarina:9389641
    Handle: https://hdl.handle.net/20.500.11797/imarina9389641
    Authors:  Obradors, C; Echavarren, AM
    Abstract:
    Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2014/cc/c3cc45518a
    APA: Obradors, C; Echavarren, AM (2014). Intriguing mechanistic labyrinths in gold(I) catalysis. Chemical Communications, 50(1), 16-28. DOI: 10.1039/c3cc45518a
    Paper original source: Chemical Communications. 50 (1): 16-28
    Article's DOI: 10.1039/c3cc45518a
    Journal publication year: 2014-01-01
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Obradors, C; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Surfaces, coatings and films, Metals and alloys, Materials chemistry, General medicine, General chemistry, Electronic, optical and magnetic materials, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Ceramics and composites, Catalysis, Biotecnología, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Terminal alkynes
    Structural-characterizatio
    Solution behavior
    Skeletal rearrangement
    Ray crystal-structures
    One-pot synthesis
    N-heterocyclic carbene
    Intermolecular 2+2 cycloaddition
    Highly efficient
    Gold(i)-catalyzed cyclizations
    Catalysis
    Ceramics and Composites
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Electronic
    Optical and Magnetic Materials
    Materials Chemistry
    Metals and Alloys
    Surfaces
    Coatings and Films
    General medicine
    General chemistry
    Chemistry (all)
    Biotecnología
    Astronomia / física

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