Articles producció científicaQuímica Analítica i Química Orgànica

Gold(I) Carbenoids: On-Demand Access to Gold(I) Carbenes in Solution

  • Identification data

    Identifier:  imarina:9440784
    Handle: https://hdl.handle.net/20.500.11797/imarina9440784
    Authors:  Sarria Toro, Juan M; Garcia-Morales, Cristina; Raducan, Mihai; Smirnova, Ekaterina S; Echavarren, Antonio M
    Abstract:
    Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily synthesized by reaction of trimethylsilyldiazomethane with the corresponding gold chloride precursors. Activation of these gold(I) carbenoids with a variety of chloride scavengers promotes reactivity typical of metallocarbenes in solution, namely homocoupling to ethylene, olefin cyclopropanation, and Buchner ring expansion of benzene.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201611705
    APA: Sarria Toro, Juan M; Garcia-Morales, Cristina; Raducan, Mihai; Smirnova, Ekaterina S; Echavarren, Antonio M (2017). Gold(I) Carbenoids: On-Demand Access to Gold(I) Carbenes in Solution. Angewandte Chemie (International Ed. Print), 56(7), 1859-1863. DOI: 10.1002/anie.201611705
    Paper original source: Angewandte Chemie (International Ed. Print). 56 (7): 1859-1863
    Article's DOI: 10.1002/anie.201611705
    Journal publication year: 2017
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Sarria Toro, Juan M; Garcia-Morales, Cristina; Raducan, Mihai; Smirnova, Ekaterina S; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Medicina ii, Medicina i, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias ii, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat

  • Keywords:

    Trimethylsilyldiazomethane
    Substitution
    Smith cyclopropanation reaction
    Reactivity
    Metathesi
    Gold
    Gol
    Gas-phase
    Decomposition
    Cyclopropanation
    Complexes
    Carbon bonds
    Carbenoids
    Carbenes
    Buchner reaction
    Aromatic-hydrocarbons
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry (all)
    Astronomia / física

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