Articles producció científicaQuímica Analítica i Química Orgànica

Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation

  • Identification data

    Identifier:  imarina:9440792
    Handle: https://hdl.handle.net/20.500.11797/imarina9440792
    Authors:  Dorel, R; de Mendoza, P; Calleja, P; Pascual, S; González-Cantalapiedra, E; Cabello, N; Echavarren, AM
    Abstract:
    The synthesis of a new C-3v-symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of a syn-trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C-60, as detected by LDI-MS.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201600311
    APA: Dorel, R; de Mendoza, P; Calleja, P; Pascual, S; González-Cantalapiedra, E; Cabello, N; Echavarren, AM (2016). Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation. European Journal Of Organic Chemistry, 2016(19), 3171-3176. DOI: 10.1002/ejoc.201600311
    Paper original source: European Journal Of Organic Chemistry. 2016 (19): 3171-3176
    Article's DOI: 10.1002/ejoc.201600311
    Journal publication year: 2016-07-01
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Dorel, R; de Mendoza, P; Calleja, P; Pascual, S; González-Cantalapiedra, E; Cabello, N; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Interdisciplinar, Chemistry, organic, Biotecnología, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Truxenes
    Truxene
    Precursors
    Palladium
    Molecules
    Mechanis
    Mass spectrometry
    Mass spectrometr
    Fullerenes
    Derivatives
    Cyclodehydrogenation
    C-60
    Building-blocks
    Arylation
    Chemistry
    Organic
    Organic Chemistry
    Physical and Theoretical Chemistry
    Interdisciplinar
    Biotecnología
    Astronomia / física

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