Articles producció científicaQuímica Analítica i Química Orgànica

Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst

  • Identification data

    Identifier:  imarina:9440795
    Handle: https://hdl.handle.net/20.500.11797/imarina9440795
    Authors:  Miller, R; Carreras, J; Muratore, ME; Gaydou, M; Camponovo, F; Echavarren, AM
    Abstract:
    A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF6 as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acs.joc.5b02607
    APA: Miller, R; Carreras, J; Muratore, ME; Gaydou, M; Camponovo, F; Echavarren, AM (2016). Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst. Journal Of Organic Chemistry, 81(5), 1839-1849. DOI: 10.1021/acs.joc.5b02607
    Paper original source: Journal Of Organic Chemistry. 81 (5): 1839-1849
    Article's DOI: 10.1021/acs.joc.5b02607
    Journal publication year: 2016-03-04
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Miller, R; Carreras, J; Muratore, ME; Gaydou, M; Camponovo, F; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Organic chemistry, General medicine, Chemistry, organic, Biotecnología
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Stereoselective-synthesis
    Rearrangemen
    Molecular complexity
    Metal-complexes
    Hydroxycyclization
    Gold complexes
    Cycloisomerization
    Cyclization
    Clean water and sanitation
    Alkoxycyclization
    6-enynes
    Chemistry
    Organic
    Organic Chemistry
    General medicine
    Biotecnología

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