Articles producció científica> Química Analítica i Química Orgànica

Intermolecular reactions of gold(I)-carbenes with furans by related mechanisms

  • Identification data

    Identifier: imarina:9440798
    Authors:
    Leboeuf, DavidGaydou, MorganeWang, YahuiEchavarren, Antonio M
    Abstract:
    The intermolecular gold(I)-catalyzed reactions of propargyl carboxylates, 1,6-enynes, or 7-substituted 1,3,5-cycloheptatrienes with furans afford cyclopentenones, polyenes or polycyclic compounds by related mechanisms initiated by the electrophilic addition of gold(I) carbenes to furans followed by ringopening.
  • Others:

    Author, as appears in the article.: Leboeuf, David; Gaydou, Morgane; Wang, Yahui; Echavarren, Antonio M
    Department: Química Analítica i Química Orgànica
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Keywords: Skeletal reorganization Retro-buchner reaction Propargylic esters Platinum catalysis Phenol synthesis Gold(i)-catalyzed cyclizations Gold catalysis Enynes Carbene-transfer Alkyne
    Abstract: The intermolecular gold(I)-catalyzed reactions of propargyl carboxylates, 1,6-enynes, or 7-substituted 1,3,5-cycloheptatrienes with furans afford cyclopentenones, polyenes or polycyclic compounds by related mechanisms initiated by the electrophilic addition of gold(I) carbenes to furans followed by ringopening.
    Thematic Areas: Organic chemistry Chemistry, organic
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: antoniomaria.echavarren@urv.cat
    Author identifier: 0000-0002-6418-7930
    Record's date: 2025-02-18
    Paper version: info:eu-repo/semantics/publishedVersion
    Paper original source: Organic Chemistry Frontiers. 1 (7): 759-764
    APA: Leboeuf, David; Gaydou, Morgane; Wang, Yahui; Echavarren, Antonio M (2014). Intermolecular reactions of gold(I)-carbenes with furans by related mechanisms. Organic Chemistry Frontiers, 1(7), 759-764. DOI: 10.1039/c4qo00130c
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2014
    Publication Type: Journal Publications
  • Keywords:

    Chemistry, Organic,Organic Chemistry
    Skeletal reorganization
    Retro-buchner reaction
    Propargylic esters
    Platinum catalysis
    Phenol synthesis
    Gold(i)-catalyzed cyclizations
    Gold catalysis
    Enynes
    Carbene-transfer
    Alkyne
    Organic chemistry
    Chemistry, organic
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