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Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis

  • Identification data

    Identifier:  imarina:9440804
    Handle: https://hdl.handle.net/20.500.11797/imarina9440804
    Authors:  Wang, YH; Muratore, ME; Rong, ZT; Echavarren, AM
    Abstract:
    7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C-1 component of the cycloaddition.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201404029
    APA: Wang, YH; Muratore, ME; Rong, ZT; Echavarren, AM (2014). Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis. Angewandte Chemie (International Ed. Print), 53(51), 14022-14026. DOI: 10.1002/anie.201404029
    Paper original source: Angewandte Chemie (International Ed. Print). 53 (51): 14022-14026
    Article's DOI: 10.1002/anie.201404029
    Journal publication year: 2014-12-15
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Wang, YH; Muratore, ME; Rong, ZT; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: General medicine, General chemistry, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Retro-buchner reaction
    Rearrangements
    Methylenecyclopropanes
    Methylenecyclopropane
    Methylene
    Metathesis
    Intramolecular (4+1)-cycloaddition
    Heterocycles
    Gold catalysis
    Generatio
    Cyclopropanation
    Cyclobutenes
    Cyclization
    Carbenes
    Carbene complexes
    (4+1) cycloaddition
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    General medicine
    General chemistry
    Chemistry (all)
    Astronomia / física

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