Articles producció científicaQuímica Analítica i Química Orgànica

Gold(I)-Catalyzed Intermolecular Reactions of Alkynes with Carbon Nucleophiles: What We Know-and What We Don't

  • Identification data

    Identifier:  imarina:9525848
    Authors:  Rodrigalvarez J; Arnanz A; Ogalla G; Echavarren AM
    Abstract:
    We present an overview of the scope, limitations, and challenges associated with gold(I)-catalyzed intermolecular reactions involving alkynes and alkenes, or alkynes with other alkynes, as well as mechanistically related transformations with a broader range of carbon-based nucleophiles. Emphasis is placed on reactivity patterns, selectivity issues, and the factors that currently limit the generality and synthetic applicability of these processes.
  • Others:

    Link to the original source: https://pubs.acs.org/accacs/article/16/8/7112/5138505/Gold-I-Catalyzed-Intermolecular-Reactions-of
    APA: Rodrigalvarez J; Arnanz A; Ogalla G; Echavarren AM (2026). Gold(I)-Catalyzed Intermolecular Reactions of Alkynes with Carbon Nucleophiles: What We Know-and What We Don't. ACS Catalysis, 16(8), 7112-7126. DOI: 10.1021/acscatal.6c00792
    Paper original source: ACS Catalysis. 16 (8): 7112-7126
    Article's DOI: 10.1021/acscatal.6c00792
    Journal publication year: 2026-03-30
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-10-10
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: info:eu-repo/semantics/article
    Author, as appears in the article.: Rodrigalvarez J; Arnanz A; Ogalla G; Echavarren AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, General chemistry, Chemistry, physical, Chemistry (miscellaneous), Chemistry (all), Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat
  • Keywords:

    Retro-buchner reaction
    Rearrangements
    Platinum
    Gold-catalyzed cycloisomerization
    Gold catalysis
    Gold carbenes
    Furans
    Cycloadditions
    Cyclization
    Complexes
    Carbenes
    Beta-ketoesters
    Alkynes
    Alkenes
    Activation
    2+2 cycloaddition
    Catalysis
    Chemistry (Miscellaneous)
    Chemistry
    Physical
    Química
    General chemistry
    Chemistry (all)
    Astronomia / física
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