Autor según el artículo: Gerard Lligadas; Marc Comí; Juan C. Ronda; Marina Galià; Virginia Cadiz

Departamento: Química Analítica i Química Orgànica

Autor/es de la URV: LLIGADAS PUIG, GERARD; Marc Comí; RONDA BARGALLÓ, JUAN CARLOS; GALIÀ CLUA, MARINA TERESA; CÁDIZ DELEITO, MARIA VIRGINIA

Palabras clave: Polyurethanes functionalization thiol-ene/yne coupling, allyl- and propargyl-containing diols

Resumen: An efficient route to obtain allyl- and propargyl-containing diols from 10-undecen-1-ol, and their polymerization with isophorone diisocyanate to produce alkene- and alkyne-functionalized polyurethanes (PUs) is described. The bio-based PUs have been further modified by thiol-ene/yne coupling of thioglycerol into unsaturation to obtain a series of PUs with enhanced hydrophilicity. All the synthesized PUs were characterized by FTIR-ATR and NMR spectroscopy. As expected, the PUs were amorphous and DSC revealed glass transition temperatures in the range of 40 °C¿5 °C for the PUs before and after modification. The PUs exhibited highly tunable thermal and mechanical properties. The mechanical properties of these bio-based polymers (E modulus from 774 MPa to 6 MPa and at break from 45% to 401%) make the suitable materials for a large range of applications.

Grupo de investigación: Polimers

Áreas temáticas: Chemistry Química Química

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 0032-3861

Identificador del autor: 0000-0002-8519-1840; n/a; 0000-0002-0668-6600; 0000-0002-4359-4510; 0000-0003-2689-5407

Fecha de alta del registro: 2016-10-10

Página final: 170

Volumen de revista: 103

Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion

Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0032386116308576?via%3Dihub

DOI del artículo: 10.1016/j.polymer.2016.09.057

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2016

Página inicial: 163

Tipo de publicación: Article Artículo Article