Articles producció científica> Enginyeria Química

Micellar morphological transformations for a series of linear diblock model surfactants

  • Datos identificativos

    Identificador: PC:863
    Handle: http://hdl.handle.net/20.500.11797/PC863
  • Autores:

    Daful, A.G.
    Mackie, A.D.
  • Otros:

    Autor según el artículo: Daful, A.G. Mackie, A.D.
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: http://scitation.aip.org/content/aip/journal/jcp/140/10/10.1063/1.4867894
    Departamento: Enginyeria Química
    DOI del artículo: 10.1063/1.4867894]
    Resumen: The concentration induced shape transitions of linear model surfactants, HxTy, on a lattice have been studied using Monte Carlo simulation. It has been found that a sphere to cylinder shape transition is generally found on shortening the hydrophilic part of the surfactant and anticipates an eventual phase transition. Asymmetric surfactants with longer heads than tails ( x > y) prefer to form only spherical micelles independent of total surfactant concentration while asymmetric surfactants with longer tails than heads ( x < y) form spherical micelles at lower concentration and undergo a shape transition to cylindrical micelles on increasing the total concentration. Finally, in the case of symmetric surfactants with x = y, only the shortest surfactants H1T1 and H2T2 undergo a sphere to cylinder shape transition on increasing surfactant concentration. Longer symmetric surfactants are always found to prefer to form spherical micelles.
    Entidad: Universitat Rovira i Virgili.
    Año de publicación de la revista: 2014
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Página inicial: 104905
    Volumen de revista: 140