Autor según el artículo: Andreozzi, Mario; Alvarez, Mayra G; Contreras, Sandra; Medina, Francesc; Clarizia, Laura; Vitiello, Giuseppe; Llorca, Jordi; Marotta, Raffaele
Departamento: Enginyeria Química
Autor/es de la URV: Contreras Iglesias, Sandra / GARCÍA ALVAREZ, MAYRA / Medina Cabello, Francisco
Palabras clave: Water reuse Tio /rgo 2 Saline produced water Produced water Photocatalysis Hydrophobic organic pollutants Graphenic materials
Resumen: © 2018 Elsevier B.V. Graphene like-TiO2nanocomposites (rGO-TiO2) are prepared via hydrothermal route by following different synthetic protocols. The as-prepared nanostructured materials exhibit higher photocatalytic activity than bare TiO2in the treatment of synthetic produced water containing high salinity levels and different compositions of recalcitrant dissolved organic matter. The effect of the preparation method on the physico-chemical properties is assessed by performing a wide characterization combining different analyses, such as nitrogen physic-adsorption (BET), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), UV-VIS Diffuse Reflectance Spectroscopy (DRUV) and Electron Paramagnetic Resonance (EPR). The effect of several operative variables (i.e., TiO2/rGO weight ratios, and addition of hydrogen peroxide) on the photocatalytic activity is also critically evaluated. The highest photocatalytic activity is obtained for a rGO/TiO2weight ratio of about 10%, for which a good compromise between uniformity of dispersion of the TiO2particles on the rGO layers and covering degree of the titania photoactive surface is achieved. This study can contribute to open new perspectives in the design of high performance graphene like-based TiO2photocatalysts for removing hydrophobic bio-recalcitrant pollutants from saline water.
Áreas temáticas: Química Materiais Interdisciplinar Geociências General chemistry Engineering, chemical Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Chemistry, applied Chemistry (miscellaneous) Chemistry (all) Catalysis Biotecnología Biodiversidade Astronomia / física Arquitetura, urbanismo e design
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 09205861
Direcció de correo del autor: sandra.contreras@urv.cat francesc.medina@urv.cat
Identificador del autor: 0000-0001-8917-4733 0000-0002-3111-1542
Fecha de alta del registro: 2024-10-12
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S0920586118305042
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Catalysis Today. 315 194-204
Referencia de l'ítem segons les normes APA: Andreozzi, Mario; Alvarez, Mayra G; Contreras, Sandra; Medina, Francesc; Clarizia, Laura; Vitiello, Giuseppe; Llorca, Jordi; Marotta, Raffaele (2018). Treatment of saline produced water through photocatalysis using rGO-TiO2nanocomposites. Catalysis Today, 315(), 194-204. DOI: 10.1016/j.cattod.2018.04.048
DOI del artículo: 10.1016/j.cattod.2018.04.048
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2018
Tipo de publicación: Journal Publications
Repositori URV