Articles producció científica> Química Física i Inorgànica

The mechanism of CO2 hydration: A porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role

  • Datos identificativos

    Identificador: imarina:5129532
    Handle: https://hdl.handle.net/20.500.11797/imarina5129532
    Autores:
    Bandeira, Nuno A. G.Garai, SomenathMueller, AchimBo, Carles
    Resumen:
    The mechanism for the hydration of CO2 within a Keplerate nanocapsule is presented. A network of hydrogen bonds across the water layers in the first metal coordination sphere facilitates the proton abstraction and nucleophilic addition of water. The highly acidic properties of the polyoxometalate cluster are crucial for explaining the catalysed hydration.

  • Otros:

    Autor según el artículo: Bandeira, Nuno A. G.; Garai, Somenath; Mueller, Achim; Bo, Carles;
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Bo Jané, Carles
    Palabras clave: Keplerate Dynamic library Dioxide Capture Ab-initio
    Resumen: The mechanism for the hydration of CO2 within a Keplerate nanocapsule is presented. A network of hydrogen bonds across the water layers in the first metal coordination sphere facilitates the proton abstraction and nucleophilic addition of water. The highly acidic properties of the polyoxometalate cluster are crucial for explaining the catalysed hydration.
    Áreas temáticas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: carles.bo@urv.cat
    Identificador del autor: 0000-0001-9581-2922
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemical Communications. 51 (85): 15596-15599
    Referencia de l'ítem segons les normes APA: Bandeira, Nuno A. G.; Garai, Somenath; Mueller, Achim; Bo, Carles; (2015). The mechanism of CO2 hydration: A porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role. Chemical Communications, 51(85), 15596-15599. DOI: 10.1039/c5cc06423f
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2015
    Tipo de publicación: Journal Publications

  • Palabras clave:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Keplerate
    Dynamic library
    Dioxide
    Capture
    Ab-initio
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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