Autor según el artículo: Isarn I., Gamardella F., Massagués L., Fernàndez-Francos X., Serra À., Ferrando F.

Departamento: Química Analítica i Química Orgànica Enginyeria Electrònica Enginyeria Mecànica

Autor/es de la URV: Fernández Francos, Xavier / Ferrando Piera, Francesc / Massagués Vidal, Lluís / Serra Albet, Maria Angels

Palabras clave: Hashtag Etiqueta «#» @uroweb @residentesaeu @infoAeu

Resumen: © 2018 Society of Plastics Engineers Thermal dissipation is a critical aspect for the performance and lifetime of electronic devices. In this work, novel composites based on a cycloaliphatic epoxy matrix and BN fillers, obtained by cationic curing of mixtures of 3,4-epoxy cyclohexylmethyl 3,4-epoxy cyclohexane carboxylate (ECC) with several amounts of hexagonal boron nitride (BN) were prepared and characterized. As cationic initiator a commercial benzylanilinium salt was used, which by addition of triethanolamine, exhibited an excellent latent character and storage stability. The effect of the formulation composition was studied by calorimetry and rheological measurements. The variation of thermal conductivity, thermal stability, thermal expansion coefficient, and thermomechanical and mechanical properties of the composites with the load of BN filler (ranging from 10 to 40 wt%) was evaluated. An improvement of an 800% (1.04 W/m·K) in thermal conductivity was reached in materials with glass transition temperatures >200°C without any loss in electrical insulation. POLYM. COMPOS., 39:E1760–E1769, 2018. © 2018 Society of Plastics Engineers.

Áreas temáticas: Química Polymers and plastics Polymer science Materials science, composites Materials chemistry Materiais Interdisciplinar General chemistry Engenharias iv Engenharias iii Engenharias ii Engenharias i Educação física Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Ceramics and composites Biotecnología Astronomia / física

ISSN: 02728397

Direcció de correo del autor: xavier.fernandez@urv.cat lluis.massagues@urv.cat f.ferrando@urv.cat angels.serra@urv.cat

Identificador del autor: 0000-0002-3492-2922 0000-0002-4197-5600 0000-0003-4450-2734 0000-0003-1387-0358

Página final: E1769

Fecha de alta del registro: 2023-02-18

Volumen de revista: 39

Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion

Enlace a la fuente original: https://onlinelibrary.wiley.com/doi/abs/10.1002/pc.24774

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Polymer Composites. 39 E1760-E1769

Referencia de l'ítem segons les normes APA: Isarn I., Gamardella F., Massagués L., Fernàndez-Francos X., Serra À., Ferrando F. (2018). New epoxy composite thermosets with enhanced thermal conductivity and high Tg obtained by cationic homopolymerization. Polymer Composites, 39(), E1760-E1769. DOI: 10.1002/pc.24774

DOI del artículo: 10.1002/pc.24774

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2018

Página inicial: E1760

Tipo de publicación: Journal Publications