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Thermal conductive composites prepared by addition of several ceramic fillers to thermally cationic curing cycloaliphatic epoxy resins

  • Datos identificativos

    Identificador: imarina:5133150
    Autores:
    Isarn I, Gamardella F, Fernàndez-Francos X, Serra À, Ferrando F
    Resumen:
    © 2019 by the authors. Novel composite coatings prepared from3,4-epoxy cyclohexylmethyl 3,4-epoxycyclohexane carboxylate (ECC) and different ceramic fillers have been prepared to improve the thermal dissipation of electronic devices. As latent cationic initiator, a benzylanilinium salt with triethanolamine has been used, which leads to a polyether matrix. Different proportions of Al 2 O 3 , AlN and SiC as fillers were added to the reactive formulation. The effect of the fillers selected and their proportions on the evolution of the curing was studied by calorimetry and rheometry. The thermal conductivity, thermal stability, thermal expansion coefficient and thermomechanical and mechanical properties of the composites were evaluated. An improvement of 820% in thermal conductivity in reference to the neat material was reached with a 75 wt % of AlN, whereas glass transition temperatures higher than 200 °C were determined in all the composites.
  • Otros:

    Autor según el artículo: Isarn I, Gamardella F, Fernàndez-Francos X, Serra À, Ferrando F
    Departamento: Química Analítica i Química Orgànica
    e-ISSN: 2073-4360
    Autor/es de la URV: Fernández Francos, Xavier / Ferrando Piera, Francesc / Serra Albet, Maria Angels
    Palabras clave: Thermosets Thermal conductivity Nanocomposites Latency Epoxy homopolymerization Cycloaliphatic epoxy resin Composites Ceramic fillers Boron-nitride latency cycloaliphatic epoxy resin composites ceramic fillers
    Resumen: © 2019 by the authors. Novel composite coatings prepared from3,4-epoxy cyclohexylmethyl 3,4-epoxycyclohexane carboxylate (ECC) and different ceramic fillers have been prepared to improve the thermal dissipation of electronic devices. As latent cationic initiator, a benzylanilinium salt with triethanolamine has been used, which leads to a polyether matrix. Different proportions of Al 2 O 3 , AlN and SiC as fillers were added to the reactive formulation. The effect of the fillers selected and their proportions on the evolution of the curing was studied by calorimetry and rheometry. The thermal conductivity, thermal stability, thermal expansion coefficient and thermomechanical and mechanical properties of the composites were evaluated. An improvement of 820% in thermal conductivity in reference to the neat material was reached with a 75 wt % of AlN, whereas glass transition temperatures higher than 200 °C were determined in all the composites.
    Áreas temáticas: Polymers and plastics Polymer science Odontología General chemistry Farmacia Engenharias ii Ciências biológicas ii Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
    Acceso a la licencia de uso: thttps://creativecommons.org/licenses/by/3.0/es/
    ISSN: 20734360
    Direcció de correo del autor: xavier.fernandez@urv.cat f.ferrando@urv.cat angels.serra@urv.cat
    Identificador del autor: 0000-0002-3492-2922 0000-0003-4450-2734 0000-0003-1387-0358
    Fecha de alta del registro: 2023-02-18
    Volumen de revista: 11
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://www.mdpi.com/2073-4360/11/1/138
    Referencia al articulo segun fuente origial: Polymers. 11 (1):
    Referencia de l'ítem segons les normes APA: Isarn I, Gamardella F, Fernàndez-Francos X, Serra À, Ferrando F (2019). Thermal conductive composites prepared by addition of several ceramic fillers to thermally cationic curing cycloaliphatic epoxy resins. Polymers, 11(1), -. DOI: 10.3390/polym11010138
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI del artículo: 10.3390/polym11010138
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2019
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry (Miscellaneous),Polymer Science,Polymers and Plastics
    Thermosets
    Thermal conductivity
    Nanocomposites
    Latency
    Epoxy homopolymerization
    Cycloaliphatic epoxy resin
    Composites
    Ceramic fillers
    Boron-nitride
    latency
    cycloaliphatic epoxy resin
    composites
    ceramic fillers
    Polymers and plastics
    Polymer science
    Odontología
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Astronomia / física
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