Articles producció científica> Química Física i Inorgànica

Multiplex SERS Chemosensing of Metal Ions via DNA-Mediated Recognition

  • Datos identificativos

    Identificador: imarina:5873586
    Autores:
    Guerrini L, Alvarez-Puebla RA
    Resumen:
    The combination of molecular sensors and plasmonic materials is emerging as one of the most promising approaches for ultrasensitive SERS-based detection of metal ions in complex fluids. However, only a very small fraction of the large pool of potential chemosensors described in classical analytical chemistry has been successfully implemented into viable SERS platforms for metal ion determination. This is due to the molecular restrictions that require the chemosensor to adhere onto the plasmonic surface while retaining the capability to undergo large structural alterations upon metal ion binding. In this work, we demonstrate that the structural and functional plasticity of DNA for interacting with small aromatic molecules can be exploited to this end. DNA coating of silver nanoparticles modulates the interaction of the commercially available alizarin red S (ARS) chemosensor with the nanomaterial, translating its recognition capabilities from bulk solution onto the plasmonic surface, while simultaneously directing the particle assembling into highly efficient SERS clusters. The sensing approach was successfully applied to the multiplex, quantitative determination of Al(III) and Fe(III) in tap water in the subppb level.
  • Otros:

    Autor según el artículo: Guerrini L, Alvarez-Puebla RA
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Alvarez Puebla, Ramon Angel / Guerrini, Luca
    Palabras clave: Surface-enhanced raman Speciation Silver Sensors Scattering analysis Quantification Design Alizarin-red-s Adsorption
    Resumen: The combination of molecular sensors and plasmonic materials is emerging as one of the most promising approaches for ultrasensitive SERS-based detection of metal ions in complex fluids. However, only a very small fraction of the large pool of potential chemosensors described in classical analytical chemistry has been successfully implemented into viable SERS platforms for metal ion determination. This is due to the molecular restrictions that require the chemosensor to adhere onto the plasmonic surface while retaining the capability to undergo large structural alterations upon metal ion binding. In this work, we demonstrate that the structural and functional plasticity of DNA for interacting with small aromatic molecules can be exploited to this end. DNA coating of silver nanoparticles modulates the interaction of the commercially available alizarin red S (ARS) chemosensor with the nanomaterial, translating its recognition capabilities from bulk solution onto the plasmonic surface, while simultaneously directing the particle assembling into highly efficient SERS clusters. The sensing approach was successfully applied to the multiplex, quantitative determination of Al(III) and Fe(III) in tap water in the subppb level.
    Áreas temáticas: Química Medicina ii Medicina i Materiais Interdisciplinar Geociências General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Enfermagem Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, analytical Biotecnología Biodiversidade Astronomia / física Analytical chemistry
    ISSN: 00032700
    Direcció de correo del autor: ramon.alvarez@urv.cat luca.guerrini@urv.cat
    Identificador del autor: 0000-0003-4770-5756 0000-0002-2925-1562
    Fecha de alta del registro: 2023-02-18
    Referencia al articulo segun fuente origial: Analytical Chemistry. 91 (18): 11778-11784
    Referencia de l'ítem segons les normes APA: Guerrini L, Alvarez-Puebla RA (2019). Multiplex SERS Chemosensing of Metal Ions via DNA-Mediated Recognition. Analytical Chemistry, 91(18), 11778-11784. DOI: 10.1021/acs.analchem.9b02385
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI del artículo: 10.1021/acs.analchem.9b02385
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2019
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Analytical Chemistry,Chemistry, Analytical
    Surface-enhanced raman
    Speciation
    Silver
    Sensors
    Scattering analysis
    Quantification
    Design
    Alizarin-red-s
    Adsorption
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    Geociências
    General medicine
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Enfermagem
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Ciência da computação
    Chemistry, analytical
    Biotecnología
    Biodiversidade
    Astronomia / física
    Analytical chemistry
  • Documentos:

  • Cerca a google

    Search to google scholar