Articles producció científica> Química Física i Inorgànica

Phosphite-thioether/selenoether Ligands from Carbohydrates: An Easily Accessible Ligand Library for the Asymmetric Hydrogenation of Functionalized and Unfunctionalized Olefins

  • Datos identificativos

    Identificador: imarina:5874010
    Autores:
    Margalef JBorràs CAlegre SAlberico EPàmies ODiéguez M
    Resumen:
    © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim A large family of phosphite-thioether/selenoether ligands has been easily prepared from accessible L-(+)-tartaric acid and D-(+)-mannitol and applied in the M-catalyzed (M=Ir, Rh) asymmetric hydrogenation of a broad number of substrates (46 in total). Its highly modular architecture has been crucial to maximize the catalytic performance. Improving most of the reported approaches, this ligand family presents a broad substrate scope. By selecting the ligand parameters high enantioselectivities (ee's up to 99 %) have therefore been achieved in a broad range of both, functionalized and unfunctionalized substrates. Interestingly, both enantiomers of the hydrogenation products can be usually achieved by changing the ligand parameters.
  • Otros:

    Autor según el artículo: Margalef J; Borràs C; Alegre S; Alberico E; Pàmies O; Diéguez M
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: ALEGRE ARAGONÉS, SABINA / BORRÀS NOGUERA, CARLOTA / Diéguez Fernández, Montserrat / Margalef Pallarès, Jèssica / Pamies Ollé, Oscar
    Palabras clave: Thioether-phosphite Substrate scope Rhodium Rh Phosphoroamidite Phosphoramidites Olefins Iridium-catalyzed hydrogenation Iridium Hydrogenation Highly enantioselective hydrogenation Enamides Complexes Asymmetric catalysis Amino
    Resumen: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim A large family of phosphite-thioether/selenoether ligands has been easily prepared from accessible L-(+)-tartaric acid and D-(+)-mannitol and applied in the M-catalyzed (M=Ir, Rh) asymmetric hydrogenation of a broad number of substrates (46 in total). Its highly modular architecture has been crucial to maximize the catalytic performance. Improving most of the reported approaches, this ligand family presents a broad substrate scope. By selecting the ligand parameters high enantioselectivities (ee's up to 99 %) have therefore been achieved in a broad range of both, functionalized and unfunctionalized substrates. Interestingly, both enantiomers of the hydrogenation products can be usually achieved by changing the ligand parameters.
    Áreas temáticas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 18673880
    Direcció de correo del autor: montserrat.dieguez@urv.cat oscar.pamies@urv.cat
    Identificador del autor: 0000-0002-8450-0656 0000-0002-2352-8508
    Página final: 2168
    Fecha de alta del registro: 2023-12-16
    Volumen de revista: 11
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Enlace a la fuente original: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201900132
    Referencia al articulo segun fuente origial: Chemcatchem. 11 (8): 2142-2168
    Referencia de l'ítem segons les normes APA: Margalef J; Borràs C; Alegre S; Alberico E; Pàmies O; Diéguez M (2019). Phosphite-thioether/selenoether Ligands from Carbohydrates: An Easily Accessible Ligand Library for the Asymmetric Hydrogenation of Functionalized and Unfunctionalized Olefins. Chemcatchem, 11(8), 2142-2168. DOI: 10.1002/cctc.201900132
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI del artículo: 10.1002/cctc.201900132
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2019
    Página inicial: 2142
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Catalysis,Chemistry, Physical,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Thioether-phosphite
    Substrate scope
    Rhodium
    Rh
    Phosphoroamidite
    Phosphoramidites
    Olefins
    Iridium-catalyzed hydrogenation
    Iridium
    Hydrogenation
    Highly enantioselective hydrogenation
    Enamides
    Complexes
    Asymmetric catalysis
    Amino
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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