Autor según el artículo: Montane, Xavier; Vilasrao Bhosale, Suryakant; Antonio Reina, Jose; Giamberini, Marta
Departamento: Enginyeria Química Química Analítica i Química Orgànica
Autor/es de la URV: Giamberini, Marta / Montané Montané, Xavier / Reina Lozano, José Antonio
Palabras clave: Polyglicydol Liquid-crystalline polymers (lcp) Biomimetic
Resumen: © 2015 Elsevier Ltd. All rights reserved. A family of self-assembling LC columnar polyethers were prepared by chemical modification of linear polyglycidol with a polymerization degree equal to 20, with the dendron 3,4,5-tris[4-(n-dodecan-1-yloxy)benzyloxy]benzoic acid by Steglich esterification. The modification degrees of the resulting LC polyethers ranged between 8 and 43%. All the obtained copolymers exhibited LC behavior and the higher the modification degree, the higher the clearing range, as expected. Mesophase self-assembling depended on the amount of dendrons introduced: in the case of modification degree ranging around 10%, the copolymers exhibited lamellar columnar structure, while for the highest modification degrees, hexagonal columnar mesophase resulted; in the case of intermediate degree of modification, the copolymers exhibited a rectangular columnar mesophase. Oriented membranes could be prepared from modified polyglycidol with different modification degrees and showed promising proton permeability values. Therefore, these materials are proposed as interesting candidates for proton transport materials.
Áreas temáticas: Química Polymers and plastics Polymer science Organic chemistry Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Biotecnología Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 00323861
Direcció de correo del autor: xavier.montane@urv.cat marta.giamberini@urv.cat joseantonio.reina@urv.cat
Identificador del autor: 0000-0002-1426-239X 0000-0001-8278-3552 0000-0002-9245-4135
Fecha de alta del registro: 2024-11-02
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S0032386115003171
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Polymer. 66 100-109
Referencia de l'ítem segons les normes APA: Montane, Xavier; Vilasrao Bhosale, Suryakant; Antonio Reina, Jose; Giamberini, Marta (2015). Columnar liquid crystalline polyglycidol derivatives: A novel alternative for proton-conducting membranes. Polymer, 66(), 100-109. DOI: 10.1016/j.polymer.2015.03.071
DOI del artículo: 10.1016/j.polymer.2015.03.071
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2015
Tipo de publicación: Journal Publications
Repositori URV