Autor según el artículo: Miralles N; Gómez J; Kleij A; Fernández E
Departamento: Química Física i Inorgànica
Autor/es de la URV: Fernández Gutiérrez, Maria Elena / Fernández López, Elena / MIRALLES PRAT, NURIA
Palabras clave: Copper-mediated sn2¿ Allyl¿boryl coupling Allyl¿alkyl coupling
Resumen: © 2017 American Chemical Society. A method for the copper-catalyzed borylmethylation and borylation of vinyl cyclic carbonates through an SN2′ mechanism is reported. These singular reactions involve selective SN2′ allylic substitutions with concomitant ring opening of the cyclic carbonate and with extrusion of CO2 and formation of a useful hydroxyl functionality in a single step. The stereoselectivity of the homoallylic borylation and allylic borylation processes can be controlled, and synthetically useful unsaturated (E)-pent-2-ene-1,5-diols and (E)-but-2-ene-1,4-diols are accessed.
Áreas temáticas: Química Physical and theoretical chemistry Organic chemistry Medicina ii Medicina i Materiais Interdisciplinar General medicine Farmacia Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, organic Biotecnología Biodiversidade Biochemistry
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 15237060
Direcció de correo del autor: mariaelena.fernandez@urv.cat
Identificador del autor: 0000-0001-9025-1791
Fecha de alta del registro: 2024-08-03
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Organic Letters. 19 (22): 6096-6099
Referencia de l'ítem segons les normes APA: Miralles N; Gómez J; Kleij A; Fernández E (2017). Copper-Mediated SN2′ Allyl-Alkyl and Allyl-Boryl Couplings of Vinyl Cyclic Carbonates. Organic Letters, 19(22), 6096-6099. DOI: 10.1021/acs.orglett.7b02947
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2017
Tipo de publicación: Journal Publications
Repositori URV