Autor según el artículo: Loiko P; Pavlyuk A; Slimi S; Solé RM; Ben Salem E; Dunina E; Kornienko A; Camy P; Griebner U; Petrov V; Díaz F; Aguiló M; Mateos X
Departamento: Química Física i Inorgànica
Autor/es de la URV: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Slimi, Sami / Solé Cartañà, Rosa Maria
Palabras clave: Transition Stimulated-emission Spectroscopy Neodymium ions Nd-yag Layered structure Laser operation Klu(wo4)(2) Kgd(wo4)(2) Ions Intensities Generation Double molybdate crystals Cut Absorption
Resumen: © 2020 Elsevier B.V. We report on the growth, structure, polarized spectroscopy and first laser operation of a double molybdate compound featuring a layered structure – the monoclinic Nd:CsGd(MoO4)2. Single-crystals of 3 at.% Nd:CsGd(MoO4)2 are grown from the flux using cesium trimolybdate (Cs2Mo3O10) as a solvent. They crystallize in the monoclinic system (sp. gr. P2/c) with lattice constants a = 9.5239(4) Å, b = 5.0752(5) Å, c = 8.0580(7) Å and β = 91.157(9)°. Nd:CsGd(MoO4)2 exhibits a perfect cleavage along the (100) plane. Polarized absorption and luminescence spectra of the Nd3+ dopant ion are measured. The maximum stimulated-emission cross-section is 29.0 × 10−20 cm2 at 1065.9 nm for light polarization E ||b. The luminescence lifetime is 145 μs. The transition probabilities are determined using the modified Judd-Ofelt theory yielding the intensity parameters Ω2 = 26.736, Ω4 = 12.736 and Ω6 = 17.771 [10−20 cm2] and α = 0.122 [10−4 cm]. Continuous-wave laser operation is achieved in cleaved single-crystal plates of Nd:CsGd(MoO4)2 yielding a maximum output power of 0.54 W at 1066 nm with a laser threshold of 70 mW, a slope efficiency η of 60.4% and a linearly polarized laser output (E ||b).
Áreas temáticas: Química Optics Odontología Medicina ii Medicina i Materiais Interdisciplinar General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Condensed matter physics Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Biotecnología Biophysics Biochemistry Atomic and molecular physics, and optics Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: sami.slimi@estudiants.urv.cat sami.slimi@estudiants.urv.cat magdalena.aguilo@urv.cat rosam.sole@urv.cat xavier.mateos@urv.cat f.diaz@urv.cat
Identificador del autor: 0000-0001-6130-9579 0000-0002-5769-4141 0000-0003-1940-1990 0000-0003-4581-4967
Fecha de alta del registro: 2024-10-19
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0022231320317609?via%3Dihub
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Journal Of Luminescence. 231 (117793):
Referencia de l'ítem segons les normes APA: Loiko P; Pavlyuk A; Slimi S; Solé RM; Ben Salem E; Dunina E; Kornienko A; Camy P; Griebner U; Petrov V; Díaz F; Aguiló M; Mateos X (2021). Growth, spectroscopy and laser operation of monoclinic Nd:CsGd(MoO4)2 crystal with a layered structure. Journal Of Luminescence, 231(117793), -. DOI: 10.1016/j.jlumin.2020.117793
DOI del artículo: 10.1016/j.jlumin.2020.117793
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Tipo de publicación: Journal Publications
Repositori URV