Articles producció científica> Química Física i Inorgànica

Pd, Cu and Bimetallic PdCu NPs Supported on CNTs and Phosphine-Functionalized Silica: One-Pot Preparation, Characterization and Testing in the Semi-Hydrogenation of Alkynes

  • Datos identificativos

    Identificador: imarina:9231660
    Autores:
    Sanchez-Resa, DanielDelgado, Jorge AFernandez-Martinez, Maria DoloresDidelot, ChloeDe Mallmann, AimerySzeto, Kai CTaoufik, MostafaClaver, CarmenGodard, Cyril
    Resumen:
    Triphenylphosphine stabilized Pd, Cu and PdCu nanocatalysts supported on carbon nanotubes (CNTs) or phosphorus functionalised silica (P-SiO2) were prepared via a one-pot methodology. The series of P-SiO2 supported catalysts evidenced metal particle sizes of metallic nanoparticles (M-NPs) between 1 and 2.4 nm, smaller than their equivalents on CNTs (2.4-2.6 nm). Such a difference in particle size as a function of the support and the metallic composition indicated the more pronounced mediation of the CNTs support during the formation of the M-NPs when compared to the P-SiO2 support. The series of supported catalysts were tested in the semi-hydrogenation of alkynes providing differences in reactivity which might be correlated with the size and composition of the M-NPs and the nature of corresponding support. The carbon supported catalysts displayed in general higher activities than those supported on silica and the bimetallic catalyst PdCu/CNTs were the most selective for the case of alkyl substituted alkynes. This catalyst could moreover be recycled several times without loss of activity nor selectivity.
  • Otros:

    Autor según el artículo: Sanchez-Resa, Daniel; Delgado, Jorge A; Fernandez-Martinez, Maria Dolores; Didelot, Chloe; De Mallmann, Aimery; Szeto, Kai C; Taoufik, Mostafa; Claver, Carmen; Godard, Cyril
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Claver Cabrero, Maria del Carmen Orosia / Fernández Martínez, María Dolores / Godard, Cyril
    Palabras clave: Structure sensitivity Sites Selective hydrogenation Phenylacetylene Pdcu Palladium nanoparticles Nanoparticles Nanocomposite Nanocatalysts Functionalized silica Design Catalysts Carbon nanotubes Alkyne semi-hydrogenation Acetylene
    Resumen: Triphenylphosphine stabilized Pd, Cu and PdCu nanocatalysts supported on carbon nanotubes (CNTs) or phosphorus functionalised silica (P-SiO2) were prepared via a one-pot methodology. The series of P-SiO2 supported catalysts evidenced metal particle sizes of metallic nanoparticles (M-NPs) between 1 and 2.4 nm, smaller than their equivalents on CNTs (2.4-2.6 nm). Such a difference in particle size as a function of the support and the metallic composition indicated the more pronounced mediation of the CNTs support during the formation of the M-NPs when compared to the P-SiO2 support. The series of supported catalysts were tested in the semi-hydrogenation of alkynes providing differences in reactivity which might be correlated with the size and composition of the M-NPs and the nature of corresponding support. The carbon supported catalysts displayed in general higher activities than those supported on silica and the bimetallic catalyst PdCu/CNTs were the most selective for the case of alkyl substituted alkynes. This catalyst could moreover be recycled several times without loss of activity nor selectivity.
    Áreas temáticas: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: mariadolores.fernandez@urv.cat mariadolores.fernandez@urv.cat mariadolores.fernandez@urv.cat cyril.godard@urv.cat carmen.claver@urv.cat
    Identificador del autor: 0000-0002-7334-3480 0000-0002-7334-3480 0000-0002-7334-3480 0000-0001-5762-4904 0000-0002-2518-7401
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Enlace a la fuente original: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.202100806
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: European Journal Of Inorganic Chemistry. 2021 (47): 4970-4978
    Referencia de l'ítem segons les normes APA: Sanchez-Resa, Daniel; Delgado, Jorge A; Fernandez-Martinez, Maria Dolores; Didelot, Chloe; De Mallmann, Aimery; Szeto, Kai C; Taoufik, Mostafa; Claver (2021). Pd, Cu and Bimetallic PdCu NPs Supported on CNTs and Phosphine-Functionalized Silica: One-Pot Preparation, Characterization and Testing in the Semi-Hydrogenation of Alkynes. European Journal Of Inorganic Chemistry, 2021(47), 4970-4978. DOI: 10.1002/ejic.202100806
    DOI del artículo: 10.1002/ejic.202100806
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2021
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry, Inorganic & Nuclear,Inorganic Chemistry
    Structure sensitivity
    Sites
    Selective hydrogenation
    Phenylacetylene
    Pdcu
    Palladium nanoparticles
    Nanoparticles
    Nanocomposite
    Nanocatalysts
    Functionalized silica
    Design
    Catalysts
    Carbon nanotubes
    Alkyne semi-hydrogenation
    Acetylene
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry, inorganic & nuclear
    Astronomia / física
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