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Weak anion-exchange mixed-mode materials to selectively extract acidic compounds by stir bar sorptive extraction from environmental waters

  • Datos identificativos

    Identificador: imarina:9242340
    Autores:
    Carles Nadal, JoanCatala-Icardo, MonicaBorrull, FrancescManuel Herrero-Martinez, JoseMaria Marce, RosaFontanals, Nuria
    Resumen:
    In this study, the first example of a polytetrafluoroethylene (PTFE)-based magnet coated with weak anion exchange (WAX) monolith as novel support for stir bar sorptive extraction (SBSE) is presented. Firstly, the PTFE magnets were properly modified and vinylized in order to immobilize polymer monoliths onto its surface. Then, a glycidyl methacrylate monolith was prepared and modified with ethylenediamine (EDA) to create weak anion exchanger via ring opening reaction of epoxy groups. The prepared covalently immobilized EDA-modified monoliths onto PTFE magnet exhibited good stability and reusability. Application of resulting material as stir bar for SBSE was investigated for a series of acidic compounds that includes acesulfame, saccharin, diclofenac or ibuprofen, among others as target compounds. Firstly, the SBSE conditions were optimized to promote the WAX interactions with the target compounds achieving recoveries from 37 to 75% and enable the selective extraction of these compounds as it provided values of% matrix effect from 17 to -13% when they were determined by SBSE followed by liquid chromatography - tandem mass spectrometry. The analytical methodology, was then validated and applied for the determination of the target solutes in environmental water samples, which were found at concentration up to 2500 ng L?1 in river waters. © 2021 Elsevier B.V.
  • Otros:

    Autor según el artículo: Carles Nadal, Joan; Catala-Icardo, Monica; Borrull, Francesc; Manuel Herrero-Martinez, Jose; Maria Marce, Rosa; Fontanals, Nuria
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: Borrull Ballarín, Francesc / Fontanals Torroja, Núria / Marcé Recasens, Rosa Maria / Nadal Lozano, Joan Carles
    Palabras clave: Weak anion-exchange materials Weak anion-exchange material Stir-bar-sorptive extraction Stir bar sorptive extraction Solid-phase extraction Selectivity Reusability Mass spectrometry Magnets Liquid chromatography-mass spectrometry Liquid chromatography - mass spectrometries Liquid chromatography Ions Ion exchange resins Extraction Ethylene diamine Environmental waters Environmental water Anion exchange material Anion exchange Acidic contaminants Acidic compounds transformation products surface modification stir bar sorptive extraction selectivity polar plasma pharmaceuticals monolithic polymer microextraction techniques liquid-chromatography liquid chromatography-mass spectrometry environmental waters coatings acidic contaminants
    Resumen: In this study, the first example of a polytetrafluoroethylene (PTFE)-based magnet coated with weak anion exchange (WAX) monolith as novel support for stir bar sorptive extraction (SBSE) is presented. Firstly, the PTFE magnets were properly modified and vinylized in order to immobilize polymer monoliths onto its surface. Then, a glycidyl methacrylate monolith was prepared and modified with ethylenediamine (EDA) to create weak anion exchanger via ring opening reaction of epoxy groups. The prepared covalently immobilized EDA-modified monoliths onto PTFE magnet exhibited good stability and reusability. Application of resulting material as stir bar for SBSE was investigated for a series of acidic compounds that includes acesulfame, saccharin, diclofenac or ibuprofen, among others as target compounds. Firstly, the SBSE conditions were optimized to promote the WAX interactions with the target compounds achieving recoveries from 37 to 75% and enable the selective extraction of these compounds as it provided values of% matrix effect from 17 to -13% when they were determined by SBSE followed by liquid chromatography - tandem mass spectrometry. The analytical methodology, was then validated and applied for the determination of the target solutes in environmental water samples, which were found at concentration up to 2500 ng L?1 in river waters. © 2021 Elsevier B.V.
    Áreas temáticas: Zootecnia / recursos pesqueiros Química Organic chemistry Nutrição Medicine (miscellaneous) Medicina veterinaria Medicina ii Medicina i Materiais Interdisciplinar Geociências General medicine Farmacia Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, analytical Biotecnología Biodiversidade Biochemistry Biochemical research methods Analytical chemistry
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: joancarles.nadal@estudiants.urv.cat joancarles.nadal@estudiants.urv.cat nuria.fontanals@urv.cat nuria.fontanals@urv.cat rosamaria.marce@urv.cat francesc.borrull@urv.cat
    Identificador del autor: 0000-0002-7534-1964 0000-0002-7534-1964 0000-0002-5667-2899 0000-0003-2718-9336
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0021967321008700?dgcid=rss_sd_all
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Journal Of Chromatography a. 1663 462748-
    Referencia de l'ítem segons les normes APA: Carles Nadal, Joan; Catala-Icardo, Monica; Borrull, Francesc; Manuel Herrero-Martinez, Jose; Maria Marce, Rosa; Fontanals, Nuria (2022). Weak anion-exchange mixed-mode materials to selectively extract acidic compounds by stir bar sorptive extraction from environmental waters. Journal Of Chromatography a, 1663(), 462748-. DOI: 10.1016/j.chroma.2021.462748
    DOI del artículo: 10.1016/j.chroma.2021.462748
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Analytical Chemistry,Biochemical Research Methods,Biochemistry,Chemistry, Analytical,Medicine (Miscellaneous),Organic Chemistry
    Weak anion-exchange materials
    Weak anion-exchange material
    Stir-bar-sorptive extraction
    Stir bar sorptive extraction
    Solid-phase extraction
    Selectivity
    Reusability
    Mass spectrometry
    Magnets
    Liquid chromatography-mass spectrometry
    Liquid chromatography - mass spectrometries
    Liquid chromatography
    Ions
    Ion exchange resins
    Extraction
    Ethylene diamine
    Environmental waters
    Environmental water
    Anion exchange material
    Anion exchange
    Acidic contaminants
    Acidic compounds
    transformation products
    surface modification
    stir bar sorptive extraction
    selectivity
    polar
    plasma
    pharmaceuticals
    monolithic polymer
    microextraction techniques
    liquid-chromatography
    liquid chromatography-mass spectrometry
    environmental waters
    coatings
    acidic contaminants
    Zootecnia / recursos pesqueiros
    Química
    Organic chemistry
    Nutrição
    Medicine (miscellaneous)
    Medicina veterinaria
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    Geociências
    General medicine
    Farmacia
    Engenharias ii
    Engenharias i
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, analytical
    Biotecnología
    Biodiversidade
    Biochemistry
    Biochemical research methods
    Analytical chemistry
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