Autor según el artículo: Alireza Zare; Xavier Montané; José Antonio Reina; Marta Giamberini
Departamento: Química Analítica i Química Orgànica Enginyeria Química
Autor/es de la URV: Giamberini, Marta / Montané Montané, Xavier / Reina Lozano, José Antonio / Zare, Alireza
Palabras clave: Wettability Poly(epichlorohydrin-co-ethylene oxide) Methanol permeability Linear sweep voltammetry Enginyeria química Dendrons Cation-exchange membrane
Resumen: In this paper, we report on the preparation and characterization of membranes out of two side-chain liquid crystalline copolymers, dendronized at two different extents (20 and 40%, CP20 and CP40, respectively). The membranes were characterized by atomic force microscopy (AFM), field-emission scanning electron microscopy (FESEM), contact angle (CA) analysis, and water uptake. Moreover, transport properties were studied by methanol and proton conductivity experiment and by linear sweep voltammetry (LSV). For the sake of comparison, the behavior of the grafted copolymers was compared with the unmodified copolyether CP0 and with Nafion 117. Results demonstrated that in CP20 and CP40, cation transport depends on the presence of defined cationic channels, not affected by water presence; the comparison between LSV experiments performed with different alkaline cations suggests that CP40 possesses channels with larger diameters and better-defined inner structures.
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: xavier.montane@urv.cat alireza.zare@urv.cat marta.giamberini@urv.cat joseantonio.reina@urv.cat
Identificador del autor: 0000-0002-1426-239X 0000-0002-6981-8914 0000-0001-8278-3552 0000-0002-9245-4135
Fecha de alta del registro: 2024-11-02
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Polymers . 13 (22): 3915-
Referencia de l'ítem segons les normes APA: Alireza Zare; Xavier Montané; José Antonio Reina; Marta Giamberini (2021). Membranes for Cation Transport Based on Dendronized Poly(epichlorohydrin-co-ethylene oxide). Part 2: Membrane characterization and transport properties. Polymers , 13(22), 3915-. DOI: 10.3390/polym13223915
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Tipo de publicación: Journal Publications
Repositori URV