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Solution-Processed Small Molecule Inverted Solar Cells: Impact of Electron Transport Layers

  • Datos identificativos

    Identificador: imarina:9261343
    Autores:
    Ramirez-Como, MagalyBalderrama, Victor SSanchez, Jose GSacramento, AngelEstrada, MagaliPallares, JosepMarsal, Lluis F
    Resumen:
    In this work, the use of poly (9,9-bis (30-(N,N-dimethylamino) propyl) -2,7-fluorene) -alt-2,7-(9,9-dioctylfluorene) (PFN) as electron transport layer (ETL) in inverted small molecule solar cells (SM-iOSCs) is analyzed. The optical and electrical characteristics obtained are compared with those obtained for similar SM-iOSCs where the ETL was zinc oxide. The p-DTS(FBTTh2)2 and PC70BM materials are used as donor and acceptor in the bulk heterojunction active layer, respectively for all devices. The photovoltaic devices exhibited a power conversion efficiency of 6.75% under 1 sun illumination. Impedance measurements were used to understand the causes that dominate the performance of the devices. We found that the loss resistance is governed by the PFN layer, which results in a lower fill factor value. Studies of atomic force microscopy, external quantum efficiency, and absorption UV-vis on the active layer have been performed to understand the effects of the charge transport dynamics on the performance of the devices.
  • Otros:

    Autor según el artículo: Ramirez-Como, Magaly; Balderrama, Victor S; Sanchez, Jose G; Sacramento, Angel; Estrada, Magali; Pallares, Josep; Marsal, Lluis F
    Departamento: Enginyeria Electrònica, Elèctrica i Automàtica
    Autor/es de la URV: BALDERRAMA VÁZQUEZ, VÍCTOR SAMUEL / Marsal Garví, Luis Francisco / Pallarès Marzal, Josep / Ramirez Como, Magaly / SANCHEZ LÓPEZ, JOSÉ GUADALUPE
    Palabras clave: Zno etl. Zinc oxide Sun Solution-processed small molecule Photovoltaic cells Pfn etl Performance evaluation P-dts(fbtth2)2:pc70bm solar cells Organic solar cells Indium tin oxide Impedance spectroscopy Ii-vi semiconductor materials High-efficiency Electron transport layer Dependence light intensity Buffer layers Absorption zno etl zno thickness solution-processed small molecule recombination pfn etl performance pc70bm p-dts(fbtth2)(2):pc70bm solar cells organic solar cells impedance spectroscopy fabrication electron transport layer donor dependence light intensity acceptor
    Resumen: In this work, the use of poly (9,9-bis (30-(N,N-dimethylamino) propyl) -2,7-fluorene) -alt-2,7-(9,9-dioctylfluorene) (PFN) as electron transport layer (ETL) in inverted small molecule solar cells (SM-iOSCs) is analyzed. The optical and electrical characteristics obtained are compared with those obtained for similar SM-iOSCs where the ETL was zinc oxide. The p-DTS(FBTTh2)2 and PC70BM materials are used as donor and acceptor in the bulk heterojunction active layer, respectively for all devices. The photovoltaic devices exhibited a power conversion efficiency of 6.75% under 1 sun illumination. Impedance measurements were used to understand the causes that dominate the performance of the devices. We found that the loss resistance is governed by the PFN layer, which results in a lower fill factor value. Studies of atomic force microscopy, external quantum efficiency, and absorption UV-vis on the active layer have been performed to understand the effects of the charge transport dynamics on the performance of the devices.
    Áreas temáticas: Engineering, electrical & electronic Electronic, optical and magnetic materials Electrical and electronic engineering Biotechnology
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: josep.pallares@urv.cat lluis.marsal@urv.cat
    Identificador del autor: 0000-0001-7221-5383 0000-0002-5976-1408
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://ieeexplore.ieee.org/document/9750114
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Ieee Journal Of The Electron Devices Society. 10 435-442
    Referencia de l'ítem segons les normes APA: Ramirez-Como, Magaly; Balderrama, Victor S; Sanchez, Jose G; Sacramento, Angel; Estrada, Magali; Pallares, Josep; Marsal, Lluis F (2022). Solution-Processed Small Molecule Inverted Solar Cells: Impact of Electron Transport Layers. Ieee Journal Of The Electron Devices Society, 10(), 435-442. DOI: 10.1109/JEDS.2022.3165315
    DOI del artículo: 10.1109/JEDS.2022.3165315
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Biotechnology,Electrical and Electronic Engineering,Electronic, Optical and Magnetic Materials,Engineering, Electrical & Electronic
    Zno etl.
    Zinc oxide
    Sun
    Solution-processed small molecule
    Photovoltaic cells
    Pfn etl
    Performance evaluation
    P-dts(fbtth2)2:pc70bm solar cells
    Organic solar cells
    Indium tin oxide
    Impedance spectroscopy
    Ii-vi semiconductor materials
    High-efficiency
    Electron transport layer
    Dependence light intensity
    Buffer layers
    Absorption
    zno etl
    zno
    thickness
    solution-processed small molecule
    recombination
    pfn etl
    performance
    pc70bm
    p-dts(fbtth2)(2):pc70bm solar cells
    organic solar cells
    impedance spectroscopy
    fabrication
    electron transport layer
    donor
    dependence light intensity
    acceptor
    Engineering, electrical & electronic
    Electronic, optical and magnetic materials
    Electrical and electronic engineering
    Biotechnology
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