Autor según el artículo: Pena, Carlos A; Puga, Alberto, V; Metlen, Andreas; Soto, Ana; Rodriguez, Hector
Departamento: Enginyeria Química
Autor/es de la URV: Puga Vaca, Alberto
Palabras clave: Microcrystalline cellulose Ionic liquids Hydrolysis Cellulose Acetates ioncell-f dissolution crystallinity
Resumen: A non-dissolving pretreatment consisting in the direct contact of cellulose and the ionic liquid tetra(n-butyl)phosphonium acetate, or its fluid mixtures with other phosphonium ionic liquids or with molecular liquids such as ethanol or DMSO, causes a reduction in the crystallinity of the popular microcrystalline cellulose-type Avicel PH-101 under mild conditions. At the same time, the degree of polymerization and the thermal stability of the pretreated Avicel remain essentially unaltered with respect to the untreated Avicel. The diminution of the crystallinity has been related to the increase of the reactivity of the pretreated Avicel samples via analysis of the kinetics of their enzymatic hydrolysis. For selected samples, this improved reactivity has been confirmed through their effective carboxymethylation under a simplified and milder reaction procedure.
Áreas temáticas: Química Polymers and plastics Polymer science Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Biomaterials Bioengineering Biochemistry & molecular biology Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: alberto.puga@urv.cat
Identificador del autor: 0000-0003-4201-2635
Fecha de alta del registro: 2024-10-26
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acs.biomac.1c01683
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Biomacromolecules. 23 (5): 1970-1980
Referencia de l'ítem segons les normes APA: Pena, Carlos A; Puga, Alberto, V; Metlen, Andreas; Soto, Ana; Rodriguez, Hector (2022). Liquid Systems Based on Tetra(n-butyl)phosphonium Acetate for the Non-dissolving Pretreatment of a Microcrystalline Cellulose (Avicel PH-101). Biomacromolecules, 23(5), 1970-1980. DOI: 10.1021/acs.biomac.1c01683
DOI del artículo: 10.1021/acs.biomac.1c01683
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2022
Tipo de publicación: Journal Publications
Repositori URV