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Significant Stability Improvement of Fullerene Organic Photovoltaics via ZnO Film Modification through the Intermittent Spray Pyrolysis Technique

  • Datos identificativos

    Identificador: imarina:9262280
    Autores:
    Moustafa, EnasMarsal, Lluis FPallares, Josep
    Resumen:
    Morphological control of the layers within the bulk heterojunction organic photovoltaics (BHJ-OPVs) is a key feature that governs their performance. In the present work, we demonstrate that zinc oxide-ZnO-interlayers sprayed via the intermittent spray pyrolysis technique, employing a low-concentration precursor solution, can yield inverted BHJ-OPVs as efficient as the standard reported ones using the conventional laboratory-scale spin-coating technique. However, we record a pioneer stability behavior of the fabricated inverted fullerene organic photovoltaics (iF-OPVs) with various sprayed ZnO conditions. Thus, after optimizing the sprayed ZnO interfacial layer morphology for the inverted PTB7-Th:PC70BM devices, by carefully inspecting the interdependence between the sprayed ZnO thin film morphology and the figures of merit of the optimized iF-OPVs, we conducted a distinct analysis on the optical and electronic properties of the fresh and degraded devices using external quantum efficiency measurements and impedance spectroscopy. Hence, we showed that the most proper ZnO microstructural morphology was obtained by spraying 25 running cycles (25R). Remarkably, we observed that 25R-ZnO-based iF-OPV devices showed a stunning stability behavior and maintained 85% of their initial power conversion efficiency even after 16.7 months without encapsulation in a dry nitrogen glovebox, demonstrating an excellent shelf stability. Accordingly, this approach might facilitate the scalability of inverted OPVs for industrial production visibility.
  • Otros:

    Autor según el artículo: Moustafa, Enas; Marsal, Lluis F; Pallares, Josep
    Departamento: Enginyeria Electrònica, Elèctrica i Automàtica
    Autor/es de la URV: Marsal Garví, Luis Francisco / Pallarès Marzal, Josep
    Palabras clave: Zno electron transporting layer Thin film deposition techniques Stability of fullerene organic photovoltaics Intermittent spray pyrolysis Electron-transport layer Degradation mechanisms in organic photovoltaics zno electron transporting layer thin film deposition techniques surface-roughness ptb7pc71bm polymer solar-cells performance intermittent spray pyrolysis impact high-efficiency enhancement degradation mechanisms in organic photovoltaics blend acceptors
    Resumen: Morphological control of the layers within the bulk heterojunction organic photovoltaics (BHJ-OPVs) is a key feature that governs their performance. In the present work, we demonstrate that zinc oxide-ZnO-interlayers sprayed via the intermittent spray pyrolysis technique, employing a low-concentration precursor solution, can yield inverted BHJ-OPVs as efficient as the standard reported ones using the conventional laboratory-scale spin-coating technique. However, we record a pioneer stability behavior of the fabricated inverted fullerene organic photovoltaics (iF-OPVs) with various sprayed ZnO conditions. Thus, after optimizing the sprayed ZnO interfacial layer morphology for the inverted PTB7-Th:PC70BM devices, by carefully inspecting the interdependence between the sprayed ZnO thin film morphology and the figures of merit of the optimized iF-OPVs, we conducted a distinct analysis on the optical and electronic properties of the fresh and degraded devices using external quantum efficiency measurements and impedance spectroscopy. Hence, we showed that the most proper ZnO microstructural morphology was obtained by spraying 25 running cycles (25R). Remarkably, we observed that 25R-ZnO-based iF-OPV devices showed a stunning stability behavior and maintained 85% of their initial power conversion efficiency even after 16.7 months without encapsulation in a dry nitrogen glovebox, demonstrating an excellent shelf stability. Accordingly, this approach might facilitate the scalability of inverted OPVs for industrial production visibility.
    Áreas temáticas: Materials science, multidisciplinary Materials chemistry Energy engineering and power technology Energy & fuels Electrochemistry Electrical and electronic engineering Chemistry, physical Chemical engineering (miscellaneous)
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: josep.pallares@urv.cat lluis.marsal@urv.cat
    Identificador del autor: 0000-0001-7221-5383 0000-0002-5976-1408
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acsaem.1c03994
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Acs Applied Energy Materials. 5 (4): 4390-4403
    Referencia de l'ítem segons les normes APA: Moustafa, Enas; Marsal, Lluis F; Pallares, Josep (2022). Significant Stability Improvement of Fullerene Organic Photovoltaics via ZnO Film Modification through the Intermittent Spray Pyrolysis Technique. Acs Applied Energy Materials, 5(4), 4390-4403. DOI: 10.1021/acsaem.1c03994
    DOI del artículo: 10.1021/acsaem.1c03994
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemical Engineering (Miscellaneous),Chemistry, Physical,Electrical and Electronic Engineering,Electrochemistry,Energy & Fuels,Energy Engineering and Power Technology,Materials Chemistry,Materials Science, Multidisciplinary
    Zno electron transporting layer
    Thin film deposition techniques
    Stability of fullerene organic photovoltaics
    Intermittent spray pyrolysis
    Electron-transport layer
    Degradation mechanisms in organic photovoltaics
    zno electron transporting layer
    thin film deposition techniques
    surface-roughness
    ptb7pc71bm
    polymer solar-cells
    performance
    intermittent spray pyrolysis
    impact
    high-efficiency
    enhancement
    degradation mechanisms in organic photovoltaics
    blend
    acceptors
    Materials science, multidisciplinary
    Materials chemistry
    Energy engineering and power technology
    Energy & fuels
    Electrochemistry
    Electrical and electronic engineering
    Chemistry, physical
    Chemical engineering (miscellaneous)
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