Autor según el artículo: Migliore, Nicola; Guzik, Aleksander; Stuart, Marc C. A.; Pala, Marc; Moreno, Adrian; Lligadas, Gerard; Raffa, Patrizio;
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: Lligadas Puig, Gerard / Moreno Guerra, Adrian / PALÀ SÁNCHEZ, MARC
Palabras clave: Thermoresponsive Self-assembly Rheology Raft polymerization Polymers Polymeric surfactants Polarity Pet-raft Green solvent Bioderived Amphiphilic random copolymers Amphiphilic polymers
Resumen: We report the synthesis and solution properties of novel biobased thermoresponsive amphiphilic copolymers prepared using N,N-dimethyl lactamide acrylate (DMLA) and ethyl lactate acrylate (ELA) as hydrophilic and hydrophobic monomers, respectively. Copolymers with similar overall molecular weight but different monomer distribution profiles, such as random, diblock, triblock, and random-blocks, were prepared using photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization activated by a Zn-based photoredox catalyst. The synthesized polymers show interesting self-assembly and thermores-ponsive behavior in water, depending on the monomers distribution along the chain. Different critical solution temperatures, in the range of 13-70 degrees C, were observed by tuning the monomers molar ratio and distribution. The formation of aggregates of various types was proven by transmission electron microscopy (TEM). The prepared polymers also display different surface activity with the fully random copolymer being significantly more surface active than block systems. A study of emulsion stabilization was performed with oils of various polarity, showing promising results for applications of these novel polymers as biobased surfactants and water/oil (w/o) emulsion stabilizers.
Áreas temáticas: Renewable energy, sustainability and the environment Química Materiais Interdisciplinar Green & sustainable science & technology General chemistry General chemical engineering Farmacia Environmental chemistry Engineering, chemical Engenharias ii Engenharias i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: marc.pala@urv.cat gerard.lligadas@urv.cat marc.pala@urv.cat adrian.moreno@urv.cat
Identificador del autor: 0000-0002-8519-1840
Fecha de alta del registro: 2024-01-13
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acssuschemeng.2c04354
URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Acs Sustainable Chemistry & Engineering.
Referencia de l'ítem segons les normes APA: Migliore, Nicola; Guzik, Aleksander; Stuart, Marc C. A.; Pala, Marc; Moreno, Adrian; Lligadas, Gerard; Raffa, Patrizio; (2022). Lactic Acid-Derived Copolymeric Surfactants with Monomer Distribution Profile-Dependent Solution and Thermoresponsive Properties. Acs Sustainable Chemistry & Engineering, (), -. DOI: 10.1021/acssuschemeng.2c04354
DOI del artículo: 10.1021/acssuschemeng.2c04354
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2022
Tipo de publicación: Journal Publications
Repositori URV