Articles producció científica> Química Física i Inorgànica

New Co and Mn Catalysts Bearing ONO Ligands Containing Nucleophile for the Coupling of CO2 and Propylene Oxide

  • Datos identificativos

    Identificador: imarina:9287715
    Autores:
    Viciano, MonicaMunoz, Bianca KZangrando, EnnioGodard, CyrilCastillon, SergioBlanco Gonzalez, Ma DoloresGarcia-Ruiz, MonicaClaver, Carmen
    Resumen:
    A series of novel ONO ligands bearing an ionic pendant-armed (hereinafter indicated as ONONu, where Nu corresponds to an anionic nucleophile) were synthesized, characterized, and successfully coordinated to cobalt and manganese precursors. New air-stable cobalt (III) complexes (1-6) and manganese (II) complexes (7 and 8) were obtained and characterized. Single crystal X-ray diffraction analysis of the Co(III) compound 5 confirmed the presence of two quaternized ligands coordinated to the metal and iodide as counterion. These novel complexes were revealed to be active catalysts in the coupling reaction of carbon dioxide and propylene oxide (PO) in different degrees of success. Among these, the manganese complex 8 afforded the best results towards the formation of propylene carbonate (PC) with a productivity of 256 kg PC/(kg cat center dot h), achieving a TON of 4860.
  • Otros:

    Autor según el artículo: Viciano, Monica; Munoz, Bianca K; Zangrando, Ennio; Godard, Cyril; Castillon, Sergio; Blanco Gonzalez, Ma Dolores; Garcia-Ruiz, Monica; Claver, Carmen
    Departamento: Química Analítica i Química Orgànica Química Física i Inorgànica
    Autor/es de la URV: Castillón Miranda, Sergio / Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
    Palabras clave: Zn(ii) complexes Structural-characterization Salen complexes Organic carbonates Ono ligands Metal al Manganese catalysts Ionic pendant-armed ligands Homogeneous catalysis Highly efficient catalysts Cyclic carbonates Crystal-structure Cobalt catalysts Co2 utilization Co2 coupling reactions Co utilization 2 Co coupling reactions 2 Carbon-dioxide Carbon dioxide Antimicrobial activity
    Resumen: A series of novel ONO ligands bearing an ionic pendant-armed (hereinafter indicated as ONONu, where Nu corresponds to an anionic nucleophile) were synthesized, characterized, and successfully coordinated to cobalt and manganese precursors. New air-stable cobalt (III) complexes (1-6) and manganese (II) complexes (7 and 8) were obtained and characterized. Single crystal X-ray diffraction analysis of the Co(III) compound 5 confirmed the presence of two quaternized ligands coordinated to the metal and iodide as counterion. These novel complexes were revealed to be active catalysts in the coupling reaction of carbon dioxide and propylene oxide (PO) in different degrees of success. Among these, the manganese complex 8 afforded the best results towards the formation of propylene carbonate (PC) with a productivity of 256 kg PC/(kg cat center dot h), achieving a TON of 4860.
    Áreas temáticas: Química Physical and theoretical chemistry Farmacia Environmental science (all) Engenharias ii Ciências biológicas ii Chemistry, physical Catalysis Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: cyril.godard@urv.cat sergio.castillon@urv.cat carmen.claver@urv.cat
    Identificador del autor: 0000-0001-5762-4904 0000-0002-0690-7549 0000-0002-2518-7401
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://www.mdpi.com/2073-4344/12/11/1443
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Catalysts. 12 (11): 1443-
    Referencia de l'ítem segons les normes APA: Viciano, Monica; Munoz, Bianca K; Zangrando, Ennio; Godard, Cyril; Castillon, Sergio; Blanco Gonzalez, Ma Dolores; Garcia-Ruiz, Monica; Claver, Carmen (2022). New Co and Mn Catalysts Bearing ONO Ligands Containing Nucleophile for the Coupling of CO2 and Propylene Oxide. Catalysts, 12(11), 1443-. DOI: 10.3390/catal12111443
    DOI del artículo: 10.3390/catal12111443
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Catalysis,Chemistry, Physical,Physical and Theoretical Chemistry
    Zn(ii) complexes
    Structural-characterization
    Salen complexes
    Organic carbonates
    Ono ligands
    Metal al
    Manganese catalysts
    Ionic pendant-armed ligands
    Homogeneous catalysis
    Highly efficient catalysts
    Cyclic carbonates
    Crystal-structure
    Cobalt catalysts
    Co2 utilization
    Co2 coupling reactions
    Co utilization 2
    Co coupling reactions 2
    Carbon-dioxide
    Carbon dioxide
    Antimicrobial activity
    Química
    Physical and theoretical chemistry
    Farmacia
    Environmental science (all)
    Engenharias ii
    Ciências biológicas ii
    Chemistry, physical
    Catalysis
    Astronomia / física
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