Articles producció científica> Química Analítica i Química Orgànica

Stabilized Lignin Nanoparticles for Versatile Hybrid and Functional Nanomaterials

  • Datos identificativos

    Identificador: imarina:9290327
    Autores:
    Morsali, MMoreno, ALoukovitou, APylypchuk, ISipponen, MH
    Resumen:
    Spherical lignin nanoparticles are emerging biobased nanomaterials, but instability and dissolution in organic solvents and aqueous alkali restrict their applicability. Here, we report the synthesis of hydroxymethylated lignin nanoparticles and their hydrothermal curing to stabilize the particles by internal cross-linking reactions. These colloidally stable particles contain a high biobased content of 97% with a tunable particle size distribution and structural stability in aqueous media (pH 3 to 12) and organic solvents such as acetone, ethanol, dimethylformamide, and tetrahydrofuran. We demonstrate that the free phenolic hydroxyl groups that are preserved in the cured particles function as efficient reducing sites for silver ions, giving rise to hybrid lignin-silver nanoparticles that can be used for quick and facile sensing of hydrogen peroxide. The stabilized lignin particles can also be directly modified using base-catalyzed reactions such as the ring-opening of cationic epoxides that render the particles with pH-dependent agglomeration and redispersion properties. Combining scalable synthesis, solvent stability, and reusability, this new class of lignin nanoparticles shows potential for its use in circular biobased nanomaterials.
  • Otros:

    Autor según el artículo: Morsali, M; Moreno, A; Loukovitou, A; Pylypchuk, I; Sipponen, MH
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: Moreno Guerra, Adrian
    Palabras clave: Silver nanoparticles Particles Amine
    Resumen: Spherical lignin nanoparticles are emerging biobased nanomaterials, but instability and dissolution in organic solvents and aqueous alkali restrict their applicability. Here, we report the synthesis of hydroxymethylated lignin nanoparticles and their hydrothermal curing to stabilize the particles by internal cross-linking reactions. These colloidally stable particles contain a high biobased content of 97% with a tunable particle size distribution and structural stability in aqueous media (pH 3 to 12) and organic solvents such as acetone, ethanol, dimethylformamide, and tetrahydrofuran. We demonstrate that the free phenolic hydroxyl groups that are preserved in the cured particles function as efficient reducing sites for silver ions, giving rise to hybrid lignin-silver nanoparticles that can be used for quick and facile sensing of hydrogen peroxide. The stabilized lignin particles can also be directly modified using base-catalyzed reactions such as the ring-opening of cationic epoxides that render the particles with pH-dependent agglomeration and redispersion properties. Combining scalable synthesis, solvent stability, and reusability, this new class of lignin nanoparticles shows potential for its use in circular biobased nanomaterials.
    Áreas temáticas: Química Polymers and plastics Polymer science Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Biomaterials Bioengineering Biochemistry & molecular biology Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: adrian.moreno@urv.cat
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acs.biomac.2c00840
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Biomacromolecules. 23 (11): 4597-4606
    Referencia de l'ítem segons les normes APA: Morsali, M; Moreno, A; Loukovitou, A; Pylypchuk, I; Sipponen, MH (2022). Stabilized Lignin Nanoparticles for Versatile Hybrid and Functional Nanomaterials. Biomacromolecules, 23(11), 4597-4606. DOI: 10.1021/acs.biomac.2c00840
    DOI del artículo: 10.1021/acs.biomac.2c00840
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Biochemistry & Molecular Biology,Bioengineering,Biomaterials,Chemistry, Organic,Materials Chemistry,Polymer Science,Polymers and Plastics
    Silver nanoparticles
    Particles
    Amine
    Química
    Polymers and plastics
    Polymer science
    Medicina ii
    Materials chemistry
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, organic
    Biotecnología
    Biomaterials
    Bioengineering
    Biochemistry & molecular biology
    Astronomia / física
  • Documentos:

  • Cerca a google

    Search to google scholar