Autor según el artículo: Santiago, David; Guzman, Dailyn; Verdugo, Pere; De la Flor, Silvia; Serra, Angels
Departamento: Química Analítica i Química Orgànica Enginyeria Mecànica
Autor/es de la URV: De la Flor Lopez, Silvia / Serra Albet, Maria Angels / Verdugo Fernandez, Pedro Manuel
Palabras clave: Vitrimers Thermosets Recycling Lightweight Glass-transition Epoxy Adhesion vitrimers transesterification thermosets temperature silica recycling lightweight fracture composite catalyst bonded joints adhesion
Resumen: Epoxy-based vitrimers represent a promising option toward sustainability and circular economy in automotive structural applications. In this work, a series of vitrimer materials are presented to be used as recyclable and reprocessable adhesives for such applications. These formulations consist of diglycidyl ether of bisphenol A-anhydride systems with glutaric anhydride and glycerol as cocuring agents in several proportions and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) or 1-methylimidazole (1MI) as catalysts. The materials obtained revealed relatively high Tg s, up to 85 °C, as well as a homogeneous network structure. They also showed complete stress relaxation in times as short as just 3.6 min at 180 °C. The presence of TBD in the vitrimer allows the fastest relaxation. The thermosets were recycled and reprocessed through alcoholysis and mechanical grinding. These formulations were also applied as adhesives for mono- and multimaterial joints showing values of single-lap shear stress as high as those shown by commercial adhesives. Reversible adhesion was also studied after joint failure and after debonding without failure. In summary, the materials and methodology presented here represent a comprehensive study of recyclable and reprocessable epoxy-based vitrimers.
Áreas temáticas: Process chemistry and technology Polymers and plastics Polymer science Organic chemistry Materials science, multidisciplinary
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: angels.serra@urv.cat silvia.delaflor@urv.cat
Identificador del autor: 0000-0003-1387-0358 0000-0002-6851-1371
Fecha de alta del registro: 2024-11-02
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acsapm.2c02063
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Acs Applied Polymer Materials. 5 (3): 2006-2015
Referencia de l'ítem segons les normes APA: Santiago, David; Guzman, Dailyn; Verdugo, Pere; De la Flor, Silvia; Serra, Angels (2023). Recyclable and Reprocessable Epoxy Vitrimer Adhesives. Acs Applied Polymer Materials, 5(3), 2006-2015. DOI: 10.1021/acsapm.2c02063
DOI del artículo: 10.1021/acsapm.2c02063
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2023
Tipo de publicación: Journal Publications