Articles producció científica> Enginyeria Química

Thermodynamic and voltammetric study on carnosine and ferrocenyl-carnosine

  • Datos identificativos

    Identificador: imarina:9292320
    Autores:
    Abate, ChiaraPiperno, AnnaFragoso, AlexGiuffre, OttaviaMazzaglia, AntoninoScala, AngelaFoti, Claudia
    Resumen:
    A potentiometric study on the interactions of L-carnosine (CAR) (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid) with two toxic metal cations, Hg2+ and Cd2+, is reported here. The elucidation of the metal (M2+)-CAR interactions in aqueous solution highlighted the speciation model for each system, the dependence of the formation constants of the complex species on ionic strength (0.15 ≤ I/mol L-1 ≤ 1) and temperature (288.15 ≤ T/K ≤ 310.15) and changes in enthalpy and entropy. The sequestering ability of CAR towards the two metal ions was quantified and compared with that with Pb2+, previously determined. Considering the complexing ability of CAR and its unclear electrochemical properties, a more electroactive derivative, the ferrocenyl-carnosine (FcCAR), was synthesized and its complexing ability was evaluated by UV-vis spectroscopy. FcCAR electrochemical properties were investigated by Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) on Screen-Printed Electrodes (SPEs), to evaluate its sensing properties. Electrochemical responses in the presence of Hg2+ and Pb2+ have been shown to be promising for the electrochemical detection of these metal cations in aqueous environment.
  • Otros:

    Autor según el artículo: Abate, Chiara; Piperno, Anna; Fragoso, Alex; Giuffre, Ottavia; Mazzaglia, Antonino; Scala, Angela; Foti, Claudia
    Departamento: Enginyeria Química
    Autor/es de la URV: Fragoso Sierra, Alex
    Palabras clave: Chemical speciation program parameters metals ligands complexes acid
    Resumen: A potentiometric study on the interactions of L-carnosine (CAR) (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid) with two toxic metal cations, Hg2+ and Cd2+, is reported here. The elucidation of the metal (M2+)-CAR interactions in aqueous solution highlighted the speciation model for each system, the dependence of the formation constants of the complex species on ionic strength (0.15 ≤ I/mol L-1 ≤ 1) and temperature (288.15 ≤ T/K ≤ 310.15) and changes in enthalpy and entropy. The sequestering ability of CAR towards the two metal ions was quantified and compared with that with Pb2+, previously determined. Considering the complexing ability of CAR and its unclear electrochemical properties, a more electroactive derivative, the ferrocenyl-carnosine (FcCAR), was synthesized and its complexing ability was evaluated by UV-vis spectroscopy. FcCAR electrochemical properties were investigated by Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) on Screen-Printed Electrodes (SPEs), to evaluate its sensing properties. Electrochemical responses in the presence of Hg2+ and Pb2+ have been shown to be promising for the electrochemical detection of these metal cations in aqueous environment.
    Áreas temáticas: Química Odontología Medicina ii Materiais Interdisciplinar Inorganic chemistry General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, inorganic & nuclear Biotecnología Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: alex.fragoso@urv.cat
    Identificador del autor: 0000-0003-4839-6094
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2023/dt/d2dt04093j
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Dalton Transactions. 52 (12): 3699-3708
    Referencia de l'ítem segons les normes APA: Abate, Chiara; Piperno, Anna; Fragoso, Alex; Giuffre, Ottavia; Mazzaglia, Antonino; Scala, Angela; Foti, Claudia (2023). Thermodynamic and voltammetric study on carnosine and ferrocenyl-carnosine. Dalton Transactions, 52(12), 3699-3708. DOI: 10.1039/d2dt04093j
    DOI del artículo: 10.1039/d2dt04093j
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2023
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry, Inorganic & Nuclear,Inorganic Chemistry
    Chemical speciation
    program
    parameters
    metals
    ligands
    complexes
    acid
    Química
    Odontología
    Medicina ii
    Materiais
    Interdisciplinar
    Inorganic chemistry
    General medicine
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, inorganic & nuclear
    Biotecnología
    Astronomia / física
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