Articles producció científica> Química Física i Inorgànica

Optical Quantification of Metal Ions Using Plasmonic Nanostructured Microbeads Coated with Metal–Organic Frameworks and Ion-Selective Dyes

  • Datos identificativos

    Identificador: imarina:9293055
    Autores:
    Zorlu, TPuértolas, BBecerril-Castro, IBGuerrini, LGiannini, VCorrea-Duarte, MAAlvarez-Puebla, RA
    Resumen:
    Herein, we designed and synthesized a hybrid material comprising polystyrene submicrobeads coated with silver nanospheres. This material provides a dense collection of electromagnetic hot spots upon illumination with visible light. The subsequent coating with a metalframework and the adsorption of bathocuproine on it yield an optical sensor for SERS that can specifically detect Cu(II) in a variety of aqueous samples at the ultratrace level. Detection limits with this method are superior to those of induced coupled plasma or atomic absorption and comparable with those obtained with induced coupled plasma coupled with a mass detector.
  • Otros:

    Autor según el artículo: Zorlu, T; Puértolas, B; Becerril-Castro, IB; Guerrini, L; Giannini, V; Correa-Duarte, MA; Alvarez-Puebla, RA
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Alvarez Puebla, Ramon Angel / Becerril Castro, Irving Brian / Guerrini, Luca / Zorlu, Tolga
    Palabras clave: Zeolitic imidazolate framework-8 Sers Plasmonic microbeads Metal−organic frameworks Metallic ions Ion-selective dyes zif-8 sers detection reagents plasmonic microbeads nanoparticles metallic ions metal-organic ion-selective dyes frameworks enhanced raman-spectroscopy copper common metals bathocuproine
    Resumen: Herein, we designed and synthesized a hybrid material comprising polystyrene submicrobeads coated with silver nanospheres. This material provides a dense collection of electromagnetic hot spots upon illumination with visible light. The subsequent coating with a metalframework and the adsorption of bathocuproine on it yield an optical sensor for SERS that can specifically detect Cu(II) in a variety of aqueous samples at the ultratrace level. Detection limits with this method are superior to those of induced coupled plasma or atomic absorption and comparable with those obtained with induced coupled plasma coupled with a mass detector.
    Áreas temáticas: Nanoscience & nanotechnology Materials science (miscellaneous) Chemistry (miscellaneous)
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: ramon.alvarez@urv.cat irvingbrian.becerril@urv.cat irvingbrian.becerril@urv.cat tolga.zorlu@estudiants.urv.cat luca.guerrini@urv.cat
    Identificador del autor: 0000-0003-4770-5756 0000-0001-7650-2152 0000-0002-2925-1562
    Fecha de alta del registro: 2024-08-03
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acsnanoscienceau.2c00063
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Acs Nanoscience Au. 3 (3): 222-229
    Referencia de l'ítem segons les normes APA: Zorlu, T; Puértolas, B; Becerril-Castro, IB; Guerrini, L; Giannini, V; Correa-Duarte, MA; Alvarez-Puebla, RA (2023). Optical Quantification of Metal Ions Using Plasmonic Nanostructured Microbeads Coated with Metal–Organic Frameworks and Ion-Selective Dyes. Acs Nanoscience Au, 3(3), 222-229. DOI: 10.1021/acsnanoscienceau.2c00063
    DOI del artículo: 10.1021/acsnanoscienceau.2c00063
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2023
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Nanoscience & Nanotechnology
    Zeolitic imidazolate framework-8
    Sers
    Plasmonic microbeads
    Metal−organic frameworks
    Metallic ions
    Ion-selective dyes
    zif-8
    sers detection
    reagents
    plasmonic microbeads
    nanoparticles
    metallic ions
    metal-organic
    ion-selective dyes
    frameworks
    enhanced raman-spectroscopy
    copper
    common metals
    bathocuproine
    Nanoscience & nanotechnology
    Materials science (miscellaneous)
    Chemistry (miscellaneous)
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