Articles producció científica> Química Física i Inorgànica

Synergistic electrodeposition of bilayer films and analysis by Raman spectroscopy

  • Datos identificativos

    Identificador: imarina:9297938
    Autores:
    Elmasly, Saadeldin E. T.Guerrini, LucaCameron, JosephKanibolotsky, Alexander L.Findlay, Neil J.Faulds, KarenSkabara, Peter J.
    Resumen:
    A novel methodology towards fabrication of multilayer organic devices, employing electrochemical polymer growth to form PEDOT and PEDTT layers, is successfully demonstrated. Moreover, careful control of the electrochemical conditions allows the degree of doping to be effectively altered for one of the polymer layers. Raman spectroscopy confirmed the formation and doped states of the PEDOT/PEDTT bilayer. The electrochemical deposition of a bilayer containing a de-doped PEDTT layer on top of doped PEDOT is analogous to a solution-processed organic semiconductor layer deposited on top of a PEDOT: PSS layer without the acidic PSS polymer. However, the poor solubility of electrochemically deposited PEDTT (or other electropolymerised potential candidates) raises the possibility of depositing a subsequent layer via solution-processing.
  • Otros:

    Autor según el artículo: Elmasly, Saadeldin E. T.; Guerrini, Luca; Cameron, Joseph; Kanibolotsky, Alexander L.; Findlay, Neil J.; Faulds, Karen; Skabara, Peter J.;
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Guerrini, Luca
    Palabras clave: Stability Raman Poly(3,4-ethylenedioxythiophene) Pedtt Pedot Multilayered films Electropolymerisation Bilayer
    Resumen: A novel methodology towards fabrication of multilayer organic devices, employing electrochemical polymer growth to form PEDOT and PEDTT layers, is successfully demonstrated. Moreover, careful control of the electrochemical conditions allows the degree of doping to be effectively altered for one of the polymer layers. Raman spectroscopy confirmed the formation and doped states of the PEDOT/PEDTT bilayer. The electrochemical deposition of a bilayer containing a de-doped PEDTT layer on top of doped PEDOT is analogous to a solution-processed organic semiconductor layer deposited on top of a PEDOT: PSS layer without the acidic PSS polymer. However, the poor solubility of electrochemically deposited PEDTT (or other electropolymerised potential candidates) raises the possibility of depositing a subsequent layer via solution-processing.
    Áreas temáticas: Química Organic chemistry Medicina i Materiais Interdisciplinar Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências ambientais Ciências agrárias i Chemistry, organic
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: luca.guerrini@urv.cat
    Identificador del autor: 0000-0002-2925-1562
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://www.beilstein-journals.org/bjoc/articles/14/191
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Beilstein Journal Of Organic Chemistry. 14 2186-2189
    Referencia de l'ítem segons les normes APA: Elmasly, Saadeldin E. T.; Guerrini, Luca; Cameron, Joseph; Kanibolotsky, Alexander L.; Findlay, Neil J.; Faulds, Karen; Skabara, Peter J.; (2018). Synergistic electrodeposition of bilayer films and analysis by Raman spectroscopy. Beilstein Journal Of Organic Chemistry, 14(), 2186-2189. DOI: 10.3762/bjoc.14.191
    DOI del artículo: 10.3762/bjoc.14.191
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2018
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry, Organic,Organic Chemistry
    Stability
    Raman
    Poly(3,4-ethylenedioxythiophene)
    Pedtt
    Pedot
    Multilayered films
    Electropolymerisation
    Bilayer
    Química
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Chemistry, organic
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