Articles producció científica> Química Física i Inorgànica

Potential of Cu-saponitecatalystsfor soot combustion

  • Datos identificativos

    Identificador: imarina:9298988
    Autores:
    Gebretsadik, F. B.Cesteros, Y.Salagre, P.Gimenez-Manogil, J.Garcia-Garcia, A.Bueno-Lopez, A.
    Resumen:
    H- and Na-saponite supports have been prepared by several synthesis approaches. 5% Cu/saponite catalysts have been prepared and tested for soot combustion in a NOx + O-2 + N-2 gas flow and with soot and catalyst mixed in loose contact mode. XRD, FT-IR, N-2 adsorption and TEM characterization results revealed that the use of either surfactant or microwaves during the synthesis led to delamination of the saponite support, yielding high surface area and small crystallite size materials. The degree of delamination affected further copper oxide dispersion and soot combustion capacity of the Cu/saponite catalysts. All Cu/saponite catalysts were active for soot combustion, and the NO2-assisted mechanism seemed to prevail. The best activity was achieved with copper oxide supported on a Na-saponite prepared at pH 13 and with surfactant. This best activity was attributed to the efficient copper oxide dispersion on the high surface area delaminated saponite (603 m(2) g(-1)) and to the presence of Na. Copper oxide reduction in H-2-TPR experiments occurred at lower temperature for the Na-containing catalysts than for the H-containing counterparts, and all Cu/Na-saponite catalysts were more active for soot combustion than the corresponding Cu/H-saponite catalysts.
  • Otros:

    Autor según el artículo: Gebretsadik, F. B.; Cesteros, Y.; Salagre, P.; Gimenez-Manogil, J.; Garcia-Garcia, A.; Bueno-Lopez, A.;
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Cesteros Fernández, Yolanda / Salagre Carnero, María Pilar
    Palabras clave: Saponite Polymer Physicochemical properties Oxidation Microwave-assisted synthesis Hectorites Emissions Clay-minerals Catalysts
    Resumen: H- and Na-saponite supports have been prepared by several synthesis approaches. 5% Cu/saponite catalysts have been prepared and tested for soot combustion in a NOx + O-2 + N-2 gas flow and with soot and catalyst mixed in loose contact mode. XRD, FT-IR, N-2 adsorption and TEM characterization results revealed that the use of either surfactant or microwaves during the synthesis led to delamination of the saponite support, yielding high surface area and small crystallite size materials. The degree of delamination affected further copper oxide dispersion and soot combustion capacity of the Cu/saponite catalysts. All Cu/saponite catalysts were active for soot combustion, and the NO2-assisted mechanism seemed to prevail. The best activity was achieved with copper oxide supported on a Na-saponite prepared at pH 13 and with surfactant. This best activity was attributed to the efficient copper oxide dispersion on the high surface area delaminated saponite (603 m(2) g(-1)) and to the presence of Na. Copper oxide reduction in H-2-TPR experiments occurred at lower temperature for the Na-containing catalysts than for the H-containing counterparts, and all Cu/Na-saponite catalysts were more active for soot combustion than the corresponding Cu/H-saponite catalysts.
    Áreas temáticas: Química Materiais Farmacia Engenharias ii Engenharias i Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: yolanda.cesteros@urv.cat
    Identificador del autor: 0000-0002-5439-9358
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2016/cy/c5cy00811e
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Catalysis Science & Technology. 6 (2): 507-514
    Referencia de l'ítem segons les normes APA: Gebretsadik, F. B.; Cesteros, Y.; Salagre, P.; Gimenez-Manogil, J.; Garcia-Garcia, A.; Bueno-Lopez, A.; (2016). Potential of Cu-saponitecatalystsfor soot combustion. Catalysis Science & Technology, 6(2), 507-514. DOI: 10.1039/C5CY00811E
    DOI del artículo: 10.1039/C5CY00811E
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2016
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Catalysis,Chemistry, Physical
    Saponite
    Polymer
    Physicochemical properties
    Oxidation
    Microwave-assisted synthesis
    Hectorites
    Emissions
    Clay-minerals
    Catalysts
    Química
    Materiais
    Farmacia
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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