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Investigating the Role of PM6:Y7 Layer Thickness on Optimizing Non-fullerene Organic Solar Cells Performance through Impedance Spectroscopy Analysis

  • Datos identificativos

    Identificador: imarina:9325781
    Autores:
    Moustafa, EnasPallares, JosepMarsal, Lluis F
    Resumen:
    Recently, there has been significant improvement in the power conversion efficiency of non-fullerene organic solar cells, exceeding 19%. In this article, we have fabricated conventional sandwich structure of ITO/PEDOT:PSS/PM6:Y7/PDINO/Ag reaching efficiency up to 17.3% along with high generated current density of 30.60 mA/cm2 for the optimized devices. The thickness of PM6:Y7 layer has been varied to investigate the impact on the overall device behavior. The obtained results showed that the PCE has been enhanced by 15% upon reducing its thickness from 150 nm to 100 nm. Accordingly, current-voltage measurements and impedance spectroscopy analysis through capacitance-voltage, Mott-Schottky analysis and capacitance frequency under different illumination intensities were conducted to evaluate the behaviour of the charge recombination due to thickness variation of the PM6:Y7 photoactive layer.
  • Otros:

    Autor según el artículo: Moustafa, Enas; Pallares, Josep; Marsal, Lluis F
    Departamento: Enginyeria Electrònica, Elèctrica i Automàtica
    Autor/es de la URV: Marsal Garví, Luis Francisco / Pallarès Marzal, Josep
    Palabras clave: Transport layer Spectroscopy Photovoltaic cells Performance evaluation Lighting Indium tin oxide Impedance spectroscopy Impedance High efficiency nonfullerene based organic solar cells Fullerenes Charge carrier recombination mechanism spectroscopy photovoltaic cells lighting indium tin oxide impedance spectroscopy impedance impact high efficiency nonfullerene based organic solar cells fullerenes fill factor energy-loss efficiency donor charge carrier recombination mechanism blend acceptor
    Resumen: Recently, there has been significant improvement in the power conversion efficiency of non-fullerene organic solar cells, exceeding 19%. In this article, we have fabricated conventional sandwich structure of ITO/PEDOT:PSS/PM6:Y7/PDINO/Ag reaching efficiency up to 17.3% along with high generated current density of 30.60 mA/cm2 for the optimized devices. The thickness of PM6:Y7 layer has been varied to investigate the impact on the overall device behavior. The obtained results showed that the PCE has been enhanced by 15% upon reducing its thickness from 150 nm to 100 nm. Accordingly, current-voltage measurements and impedance spectroscopy analysis through capacitance-voltage, Mott-Schottky analysis and capacitance frequency under different illumination intensities were conducted to evaluate the behaviour of the charge recombination due to thickness variation of the PM6:Y7 photoactive layer.
    Áreas temáticas: Engineering, electrical & electronic Electronic, optical and magnetic materials Electrical and electronic engineering Biotechnology
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: josep.pallares@urv.cat lluis.marsal@urv.cat
    Identificador del autor: 0000-0001-7221-5383 0000-0002-5976-1408
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Ieee Journal Of The Electron Devices Society. 11 642-649
    Referencia de l'ítem segons les normes APA: Moustafa, Enas; Pallares, Josep; Marsal, Lluis F (2023). Investigating the Role of PM6:Y7 Layer Thickness on Optimizing Non-fullerene Organic Solar Cells Performance through Impedance Spectroscopy Analysis. Ieee Journal Of The Electron Devices Society, 11(), 642-649. DOI: 10.1109/JEDS.2023.3294888
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2023
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Biotechnology,Electrical and Electronic Engineering,Electronic, Optical and Magnetic Materials,Engineering, Electrical & Electronic
    Transport layer
    Spectroscopy
    Photovoltaic cells
    Performance evaluation
    Lighting
    Indium tin oxide
    Impedance spectroscopy
    Impedance
    High efficiency nonfullerene based organic solar cells
    Fullerenes
    Charge carrier recombination mechanism
    spectroscopy
    photovoltaic cells
    lighting
    indium tin oxide
    impedance spectroscopy
    impedance
    impact
    high efficiency nonfullerene based organic solar cells
    fullerenes
    fill factor
    energy-loss
    efficiency
    donor
    charge carrier recombination mechanism
    blend
    acceptor
    Engineering, electrical & electronic
    Electronic, optical and magnetic materials
    Electrical and electronic engineering
    Biotechnology
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