Autor según el artículo: Guerrero, Federico; De la Flor, Silvia; Serra, Angels
Departamento: Enginyeria Mecànica
Autor/es de la URV: De la Flor Lopez, Silvia / Guerrero Ruiz, Federico / Serra Albet, Maria Angels
Palabras clave: 1,6-hexamethylene diisocyanate Catalysis Covalent adaptable networks Isocyanates Lanthanum Molecular structure Poly(isocyanurates) Poly(thiourethanes) Polyurethanes Recyclability Self-healin Self-healing Self‐healing Thermosets Triazines Trimerizatio
Resumen: Poly(thiourethane)-based covalent adaptable networks are synthesized by reacting a trimer of hexamethylene diisocyanate (Desmodur N3300) containing isocyanurate groups in its structure with 1,6-hexanedithiol. The catalysts evaluated for this process include dibutyltin dilaurate (DBTDL), lanthanum triflate (La(OTf)3), and a thermal precursor of 1,8-diazabicyclo[5.4.0]undec-7-ene (BGDBU). The use of DBTDL results in the initiation of curing upon mixing, while the other two catalysts exhibit a latency period in the reactive mixture, with curing starting at about 90 degrees C. Notably, the use of the lanthanum salt produces an additional minor exothermic reaction at 80 degrees C. This phenomenon corresponds to the trimerization of isocyanates rending isocyanurates, leaving a portion of unreacted thiols. Materials prepared with BGDBU or La(OTf)3 present shorter relaxation times than those prepared with DBTDL. Nevertheless, the materials containing the lanthanum salt do not reach complete relaxation, likely due to the reinforcement of the permanent network through increased isocyanurate content. The formation of isocyanurates produces a stoichiometric imbalance, leaving unreacted thiols. This transforms the exchange process into a dual mechanism involving a dissociative process of thiourethanes to isocyanate and thiol, along with an interchange through thiol attacking the thiourethane group. The materials exhibit good recyclability and self-healing characteristics. Poly(thiourethane)-poly(isocyanurate) covalent adaptable networks are prepared for the first time using an industrially available triisocyanate. The study examines the impact of various catalysts (1,8-diazabicyclo[5.4.0]undec-7-ene, dibutyltin dilaurate, and lanthanum triflate) and their concentrations on the material's properties. Results reveal the recyclability of the cross-linked network and its self-healing capabilities. image
Áreas temáticas: Engenharias ii Materiais Materials chemistry Organic chemistry Polymer science Polymers and plastics Química
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: silvia.delaflor@urv.cat federico.guerrero@estudiants.urv.cat federico.guerrero@estudiants.urv.cat angels.serra@urv.cat
Identificador del autor: 0000-0002-6851-1371 0000-0001-7163-4068 0000-0001-7163-4068 0000-0003-1387-0358
Fecha de alta del registro: 2024-11-02
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Referencia al articulo segun fuente origial: Macromolecular Rapid Communications. 45 (19): e2400330-
Referencia de l'ítem segons les normes APA: Guerrero, Federico; De la Flor, Silvia; Serra, Angels (2024). Preparation and Characterization of Novel Poly(thiourethane)-Poly(isocyanurate) Covalent Adaptable Networks: Effect of the Catalysts. Macromolecular Rapid Communications, 45(19), e2400330-. DOI: 10.1002/marc.202400330
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2024
Tipo de publicación: Journal Publications
Repositori URV