Meeting the Challenge of Intermolecular Gold(I)-Catalyzed Cycloadditions of Alkynes and Allenes

Identificador:  imarina:9440805

Handle: https://hdl.handle.net/20.500.11797/imarina9440805

Autores:  Muratore, Michael E; Homs, Anna; Obradors, Carla; Echavarren, Antonio M

Resumen:
The development of gold(I)-catalyzed intermolecular carbo-and hetero-cycloadditions of alkynes and allenes has been more challenging than their intramolecular counterparts. Here we review, with a mechanistic perspective, the most fundamental intermolecular cycloadditions of alkynes and allenes with alkenes.