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Iridium-Catalyzed Asymmetric Hydrogenation

  • Identification data

    Identifier: imarina:9187289
    Authors:
    Diéguez Fernández, Montserrat / Pamies Ollé, Oscar
    Abstract:
    In this chapter, we describe the development in homogeneous Ir-catalyzed asymmetric hydrogenation with particular emphasis on the achievements made during the last 10 years. We also present their application to the synthesis of complex molecules. The first section deals with the hydrogenation of unfunctionalized olefins or with poorly coordinative groups. The second section includes the advances made in the hydrogenation of functionalized olefins. The last two sections cover the hydrogenation of imines and ketones, respectively.
  • Others:

    Is part of: Topics In Organometallic Chemistry
    Departament: Química Física i Inorgànica Química Física i Inorgànica
  • Keywords:

    Catalysis,Chemistry, Inorganic & Nuclear,Chemistry, Organic,Inorganic Chemistry,Organic Chemistry
    Ketones
    Iridium
    Imines
    Highly enantioselective hydrogenation
    Catalysis
    Asymmetric hydrogenation
    (un)functionalized olefins
    selective catalysts
    proline-based p,o
    phosphite-oxazoline ligands
    minimally functionalized olefins
    ketones
    iridium
    imines
    efficient approach
    cyclic beta-enamides
    chiral 1,2-amino alcohols
    catalysis
    asymmetric hydrogenation
    alpha-hydroxy ketones
    alpha,beta-unsaturated carboxylic-acids
    Organic chemistry
    Inorganic chemistry
    Chemistry, organic
    Chemistry, inorganic & nuclear
    Catalysis
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