Cobalt nanoparticles for Fischer-Tropsch Synthesis: from colloidal to well-defined supported nanocatalysts

Identificador:  TDX:1979

Handle: https://hdl.handle.net/20.500.11797/TDX1979

Autors:  Delgado Delgado, Jorge Alonso

Resum:
The present thesis consisted in the design of novel cobalt nanocatalysts for the Fishcer-Tropsch (FT) synthesis. Cobalt nanoparticles were synthesized using different methodologies: chemical reduction method using sodium borohydride as reducing agent or thermal decomposition of organometallic precursors such as Co2(CO)8. The syntheses were carried out under the presence of polymer stabilizers. After the synthesis, the cobalt nanoparticles were isolated, characterized (using TEM, HR-TEM, XRD, XPS, ICP, FTIR, TGA and RAMAN) and tested in the Aqueous Phase Fischer-Tropsch synthesis. For comparison purposes with classical supported catalysts, the cobalt nanoparticles were also immobilized on TiO2 and tested in FT using fixed bed reactors. In this study was observed that the catalytic performance (activity and selectivity) of the cobalt nanoparticles in both catalytic systems were highly dependent on parameters such as the synthetic methodology, the polymer stabilizer and the particle size. These differences were attributed to variations in the structure and composition of the NPs intrinsic to each parameter under study.