Treatment of biorefractory wastewater through membrane-assisted oxidation processes

Identificador:  TDX:365

Handle: https://hdl.handle.net/20.500.11797/TDX365

Autors:  Bernat Camí, Xavier

Resum:
Water scarcity is one of the major challenges for assuring a sustainable development. Among other measures, research into efficient wastewater treatment systems to deal with biorefractory wastewaters, which need to be amended before their biological degradation, is required. The Fenton process is an advanced oxidation process that can be used as potential pre-treatment for this purpose. However, the pre-treatment presents two main limitations: the use of iron salts as homogeneous catalyst, which are continuously thrown away in the reactor effluent, and the high consumption of oxidant, which is partially wasted. The present thesis aims at studying the improvement of the Fenton process applied on phenolic wastewater through its coupling with membrane technologies such as nanofiltration, membrane emulsification or membrane reactors. The coupling allows confining the catalyst and increasing the oxidation efficiency, thus enhancing the treatment efficiency in environmental and economic terms.